研究業績
学術論文
2025
- Tetrabutylammonium Chlorite as an Efficient Oxidant for Controlled Oxidation of Sulfides to Sulfoxides
Itabashi, Y.; Ogata, S.; Shimada, Y.; Kondo, M.; Nishiwaki, N.; Inoue, T.; Asahara, H.; Ohkubo, K.
Chem. –Eur. J. 2025, 31, e202404279.
2024
- Photocatalytic and highly regioselective H/D exchange at alpha-thio C (sp3)-H bonds
Ogasahara, R.; Mae, M.; Itabashi, Y.; Ohkubo, K.; Matsuura, K.; Shimizu, H.; Ban, K.; Udagawa, T.; Fujioka, H.; Kamiya, M.; Akai, S.; Sawama Y.
ChemRxiv - Antioxidant Activity of Planar Catechin Conjugated with Trolox
Shimizu, W.; Shoji, Y.; Ohkubo, K.; Ito, H.; Nakanishi, I.; Fukuhara, K.
Antioxidants 2024, 13, 1165. - Construction of a screening system for lipid-derived radical inhibitors and validation of hit compounds to target retinal and cerebrovascular diseases
Mori, R; Abe, M; Saimoto, Y; Shinto, S; Jodai, S; Tomomatsu, M; Tazoe, K; Ishida, M; Enoki, M; Kato, N; Yamashita, T.; Itabashi, Y.; Nakanishi, I.; Ohkubo, K.; Kaidzu, S.; Tanito, M.; Matsuoka, Y.; Morimoto, K.; Yamada, K.
Redox Biol. 2024, 73, 103186. - Scandium Ion-Promoted Electron-Transfer Disproportionation of 2-Phenyl-4,4,5,5-tetramethylimidazoline-1-oxyl 3-Oxide (PTIO•) in Acetonitrile and Its Regeneration Induced by Water
Shoji, Y.; Terashima, Y.; Ohkubo, K.; Ito, H.; Maruyama, K.; Fukuzumi, S.; Nakanishi, I.
Int. J. Mol. Sci. 2024, 25, 4417. - 9-(4-Halo-2,6-xylyl)-10-methylacridinium Ion as an Effective Photoredox Catalyst for Oxygenation and Trifluoromethylation of Toluene Derivatives
Ohkubo, K.; Matsumoto, S.; Asahara, H.; Fukuzumi, S.
ACS Catal. 2024, 14, 2671–2684. - Mitochondria Play Essential Roles in Intracellular Protection against Oxidative Stress—Which Molecules among the ROS Generated in the Mitochondria Can Escape the Mitochondria and Contribute to Signal Activation in Cytosol?
Masuda, D.; Nakanishi, I.; Ohkubo, K.; Ito, H.; Matsumoto, K.-i.; Ichikawa, H.; Chatatikun, M.; Klangbud, W. K.; Kotepui, M.; Imai, M.; Kawakami, F.; Kubo, M.; Matsui, H.; Tangpong, J.; Ichikawa, T.; Ozawa, T.; Yen, H.-C.; St Clair, D. K.; Indo, H. P.; Majima, H.
J. Biomol. 2024, 14, 128. - Supramolecular Nanosheet Formation Induced Photosensitisation Mechanism Change of Rose Bengal Dye in Aqueous Media
Bunno, A.; Shigemitsu, H.; Yoshikawa, A.; Osakada, Y.; Fujitsuka, M.; Ishiwari, F.; Nishikubo, R.; Saeki, A.; Ohkubo, K.; Mori, T.; Kida, T.
Chem. Commun. 2024, 60, 889-892.
2023
- A BODIPY-picolinium-cation Conjugate as a Blue- light-responsive Caged Group
Ieda, N.; Nakamura, A.; Tomita, N.; Ohkubo, K.; Izumi, R.; Hotta, Y.; Kawaguchi, M.; Kimura, K.; Nakagawa, H.
RSC Adv. 2023, 13, 26375-26379. - Water-Induced Regeneration of a 2,2-Diphenyl-1-picrylhydrazyl Radical after Its Scandium Ion-Promoted Electron-Transfer Disproportionation in an Aprotic Medium
Nakanishi, I.; Shoji, Y.; Ohkubo, K.; Ito, H.; Fukuzumi, S.
Molecules, 2023, 28, 5002. - 2-Azafluorenone Derivatives: Photocatalyst for Oxygenation of Toluene via Electron Transfer and Hydrogen-Atom Transfer
Asahara, K.; Horikawa, Y.; Iwai, K.; Nishiwaki, N.; Ohkubo, K.
J. Photochem. Photobiol. 2023, 15, 100184. - One-step Antibacterial Mmodification of Polypropylene Nonwoven Fabrics via Oxidation Using Photo-activated Chlorine Dioxide Radical
Yamamoto, K.; Asahara, H.; Harada, K.; Itabashi, Y.; Ohkubo, K.; Inoue, T.
J. Mater. Chem. B 2023, 11, 5101-5107. - In vitro Radical-Scavenging Mechanism of Melatonin and its in vivo Protective Effect Against Radiation-Induced Lipid Peroxidation
Manda, K.; Ohkubo, K.; Shoji, Y.; Zoardar, A. K. M. R. K.; Kamibayashi, M.; Ozawa, T.; Anzai K.; Nakanishi, I.
Redox Biochem. Chem. 2023, 3-4, 100003.
2022
- One-pot Chlorocarboxylation of Toluenes with Chlorine Dioxide under Photoirradiation
Ohno, S.; Asahara, H.; Inoue, T.; Ohkubo, K.
RSC Adv. 2022, 12, 31412–31414. - Amphiphilic Rhodamine Nano-assembly as a Type I Supramolecular Photosensitizer for Photodynamic Therapy
Shigemitsu, H.; Sato, K.; Hagio, S.; Tani, Y.; Mori, T.; Ohkubo, K.; Osakada, Y.; Fujitsuka, M.; Kida, T.
ACS Appl. Nano Mater. 2022, 5, 14954–14960. - Pathological Complete Remission of Relapsed Tumor by Photo-Activating Antibody–Mimetic Drug Conjugate Treatment
Kaneko, Y.; Yamatsugu, K.; Yamashita, T.; Takahashi, K.; Tanaka, T.; Aki, S.; Tatsumi, T.; Kawamura, T.; Miura, M.; Ishii, M.; Ohkubo, K.; Osawa, T.; Kodama, T.; Ishikawa, S.; Tsukagoshi, M.; Chansler, M.; Sugiyama, A.; Kanai, M.; Katoh, H.
Cancer Sci. 2022, 113, 4350-4362. - Ascorbate-assisted Nitric Oxide Release from Photocontrollable Nitrosonium Ion Releasers for Potent ex vivo Photovasodilation
Ieda, N.; Yoshikawa, Y.; Tomita, N.; Ohkubo, K.; Hotta, Y.; Kawaguchi, M.; Kimura, K.; Nakagawa, H.
Chem. Commun. 2022, 58, 8420-8423. - 9‑Cyano-10-methoxycarbonylanthracene as a Visible Organic Photoredox Catalyst in the Two-Molecule Photoredox System
Tajimi, Y.; Nachi, Y.; Inada, R.; Hashimoto, R.; Yamawaki, M.; Ohkubo, K.; Morita, T.; Yoshimi, Y.
J. Org. Chem. 2022, 87, 7405-7413. - A Fluorescein based Type I Supramolecular Photosensitizer via Induction of Charge Separation by Self-Assembly
Shigemitsu, H.; Ohkubo, K.; Bunno, A.; Mori, T.; Osakada, Y.; Fujitsuka, M.; Kida, T.
J. Am. Chem. Soc. Au, 2022, 2, 1472–1478. - Visible-light-Induced Phosgenation Reaction of Amines by Oxygenation of Chloroform Using Chlorine Dioxide
Asahara, H.; Takao, N.; Moriguchi, M.; Inoue, T. Ohkubo, K.
Chem. Commun. 2022, 58, 6176 – 6179. - Effect of Magnesium Ion on the Radical-Scavenging Rate of Pterostilbene in an Aprotic Medium: Mechanistic Insight into the Antioxidative Reaction of Pterostilbene
Nakanishi, I.; Shoji, Y.; Ohkubo, K.; Ueno, M.; Shimoda, K.; Matsumoto, K.; Fukuhara, K.; Hamada, H.
Antioxidant, 2022, 11, 340. - Acridinium Salts as Photoredox Organocatalysts for Photomediated Cationic RAFT and DT Polymerizations of Vinyl Ethers
Matsuda, M.; Uchiyama, M.; Itabashi, Y.; Ohkubo, K.; Kamigaito, M.
Polym. Chem. 2022, 13, 1031-1039. - Antibody Mimetic Drug Conjugate Manufactured by High-yield Escherichia coli Expression and Non-covalent Binding System
Yamatsugu, K.; Katoh, H.; Yamashita, T.; Takahashi, K.; Aki, S.; Tatsumi, T.; Kaneko, Y.; Kawamura, T.; Miura, M.; Ishii, M.; Ohkubo, K.; Osawa, T.; Kodama, T.; Ishikawa, S.; Kanai, M.; Sugiyama, A.
Protein Expr. Purif. 2022, 192, 106043. - Laser Flash Photolytic Generation of Radical Ions of Carotenoids in Organic Solvents. Studies of Their Subsequent Fates, Including Formation of Stable Carotenoid Sigma Dimer Radical Anion (CAR)2•–
El-Agamey, A.; Melø, T. B.; Nagvi, K. R.; El-Hagrasy, M. A.; Ohkubo, K.; Fukuzumi, S.
J. Photochem. Photobiol. A 2022, 425, 113707.
2021
- Tunneling in the Hydrogen-Transfer Reaction from a Vitamin E Analog to an Inclusion Complex of 2,2-Diphenyl-1-picrylhydrzyl Radical with b-Cyclodextrin in an Aqueous Buffer Solution at Ambient Temperature
Nakanishi, I.; Shoji, Y.; Ohkubo, K.; Fukuzumi, S.
Antioxidant 2021, 10, 1966. - UV-induced Oxygenation of Toluene Catalyzed by Co(acac)2 and 9-Mesityl-10-methylacridinium Ion Mediated with NHPI
Pokutsa, A.; Ohkubo, K.; Zaborovskyi, A.; Bloniarz, P.; Мuzart, J.
Asia-Pac. J. Chem. Eng. 2021, 16, e2714. - A Cyanine Dye Based Supramolecular Photosensitizer Enabling Visible-light-driven Organic Reaction in Water
Shigemitsu, H.; Tamemoto, T.; Ohkubo, K.; Mori, T.; Osakada, Y.; Fujitsuka, M.; Kida, T.
Chem. Commun. 2021, 32, 1098-1103. - Axially Substituted Silicon Phthalocyanine Payloads for Antibody–Drug Conjugates
Takahashi, K.; Sugiyama, A.; Ohkubo, K.; Tatsumi, T.; Kodama, T.; Yamatsugu, K.; Kanai, M.
Synlett. 2021, 32, 1098-1103. - Anionic Fluorinated Zn-porphyrin Combined with Cationic Endohedral Li-fullerene for Long-Lived Photoinduced Charge Separation with Low Energy Loss
Miwa, K.; Aoyagi, S.; Sasamori, T.; Ueno, H.; Okada, H.; Ohkubo, K.
J. Phys. Chem. B 2021, 125, 918-925. - Effects of Reaction Environments on Radical-scavenging Mechanisms of Ascorbic Acid
Nakanishi, I.; Shoji, Y.; Ohkubo, K.; Fukuhara, K.; Ozawa, T.; Matsumoto, K.; Fukuzumi, S.
J. Clin. Biochem. Nutr. 2021, 68, 116-122.
2020
- Phenylene-bridged Bis(benzimidazolium) (BBIm2+): A Dicationic Organic Photoredox Catalyst
Kodama, T.; Kubo, M.; Shinji, W.; Ohkubo, K.; Tobisu, M.
Chem. Sci. 2020, 11, 12109-12117. - A Large Kinetic Isotope Effect in the Reaction of Ascorbic acid with 2-Phenyl-4,4,5,5-tetramethylimidazoline-1-oxyl 3-oxide (PTIO•) in Aqueous Buffer Solutions
Nakanishi, I.; Shoji, Y.; Ohkubo, K.; Ozawa, T.; Matsumoto, K.; Fukuzumi, S.
Chem. Commun. 2020, 51, 11505-11507. - Relationship between the Radical-Scavenging Activity of Selected Flavonols and Thermodynamic Parameters Calculated by Density Functional Theory
Nakanishi, I.; Ohkubo, K.; Fujitaka, Y.; Shimoda, K.; Matsumoto, K.; Fukuhara, K.; Hamada, H.
Free Radic. Res. 2020, 54, 535-539. - Two Different Multiple Photosynthetic Reaction Centers using either Zinc Porphyrinic Oligopeptide-Fulleropyrrolidine or Free-Base Porphyrinic Polypeptide-Li+@C60 Supramolecular Complexes
Solladié, N.; Fukuzumi, S.; Ohkubo, K.; D’Souza, F.; Rein, R.; Troiani, V.; Qiu, H.; Saito, K.; Suresh, G.; Hasegawa, T.
ECS J. Solid. State Sci. Tech. 2020, 9, 061026. - Low Switching Voltage, High-stability Organic Phototransistor Memory Based on a Photoactive Dielectric and an Electron Trapping Layer
Dao, T. T.; Sakai, H.; Ohkubo, K.; Fukuzumi, S.; Murata, H.
Org. Electron. 2020, 77, 105505.
2019
- Kinetic Isotope Effect in the Reaction of Water Soluble Antioxidants with Water-Solubilized 2,2Diphenyl-l-picrylhydrazyl Radical in Aqueous Buffer Solutions
Nakanishi, I.; Yoshimi, S.; Ohkubo, K.; Ozawa, T.; Matsumoto, K.
Free Rad. Biol. Med. 2019, 145, S34 - A Pyropheophorbide Analogue Containing a Fused Methoxy Cyclohexanone Ring System Shows Promising Cancer-Imaging Ability
Marko, A. J.; Dukh, M.; Patel, N. J.; Missert, J. R.; Ohulchanskyy, T.; Tabaczynski, W. A.; Ohkubo, K.; Fukuzumi, S.; Yai, R.; Sajjad, M.; Pandey, R. K.
ChemMedChem 2019, 14, 1503-1513. - A Diprotonated Porphyrin as an Electron Mediator in Photoinduced Electron Transfer in Hydrogen-Bonded Supramolecular Assemblies
Suzuki, W.; Kotani, H.; Ishizuka, T.; Kawano, M.; Sakai, H.; Hasobe, T.; Ohkubo, K.; Fukuzumi, S.; Kojima, T.
J. Phys. Chem. C 2019, 123, 11529-11538. - Synthesis and Radical-Scavenging Activity of C-methylated Fisetin Analogues
Imai, K.; Nakanishi, I.; Ohkubo, K.; Ohno, A.; Mizuno, M.; Fukuzumi, S.; Matsumoto, K.; Fukuhara, K.
Bioorg. Med. Chem. 2019, 27, 1720-1727. - Photochemical C–H Oxygenation of Side-chain Methyl Groups in Polypropylene with Chlorine Dioxide
Ohkubo, K.; Asahara, H.; Inoue, T.
Chem. Commun. 2019, 55, 4723-4726. - Paddlewheel Complexes with Azulenes: Electronic Interaction between Metal Centers and Equatorial Ligands
Tsuchiya, T.; Umemura, R.; Kaminaga, M.; Kushida, S.; Ohkubo, K.; Noro, S.; Mazaki, Y.
ChemPlusChem 2019, 84, 655-664. - Catalytic Asymmetric Allylation of Aldehydes with Alkenes through Allylic C(sp3)-H Functionalization Mediated by Organophotoredox and Chiral Chromium Hybrid Catalysis
Mitsunuma, H.; Tanabe, S.; Fuse, H. Ohkubo, K.; Kanai, M.
Chem. Sci. 2019, 10, 3459-3465. - Unified Mechanism of Oxygen Atom Transfer and Hydrogen Atom Transfer Reactions with a Triflic Acid-Bound Nonheme Manganese(IV)-Oxo Complex via Outer-Sphere Electron Transfer
Lee, Y.-M.; Kim, S.; Ohkubo, K.; Kim, K.-H.; Nam, W.; Fukuzumi, S.
J. Am. Chem. Soc. 2019, 141, 2614-2622.
2018
- Long-Lived Photoexcited State of a Mn(IV)-Oxo Complex Binding Scandium Ions That is Capable of Hydroxylating Benzene
Sharma, N.; Jung, J.; Ohkubo, K.; Lee, Y.-M.; El-Khouly, M. E.; Nam, W.; Fukuzumi, S.
J. Am. Chem. Soc. 2018, 140, 8405-8409. - Mechanistic Insights into Homogeneous Electrocatalytic and Photocatalytic Hydrogen Evolution Catalyzed by High-Spin Ni(II) Complexes with S2N2-Type Tetradentate Ligands
Hong, D.; Tsukakoshi, Y.; Kotani, H.; Ishizuka, T.; Ohkubo, K.; Shiota, Y.; Yoshizawa, K.; Fukuzumi, S.; Kojima, T.
Inorg. Chem. 2018, 57, 7180-7190. - A Supramolecular Photocatalyst Composed of a Polyoxometalate and a Photosensitizing Water-soluble Porphyrin Diacid for the Oxidation of Organic Substrates in Water
Ishizuka, T.; Ohkawa, S.; Ochiai, H.; Hashimoto, M.; Ohkubo, K.; Kotani, H.; Sadakane, M.; Fukuzumi, S.; Kojima, T.
Green Chem. 2018, 20, 1975-1980. - Assemblies of Boron Dipyrromethene/Porphyrin, Phthalocyanine, and C60 Moieties as Artificial Models of Photosynthesis: Synthesis, Supramolecular Interactions, and Photophysical Studies
Chen, X.-F.; El-Khouly, M. E.; Ohkubo, K.; Fukuzumi, S.; Ng, D. K. P.
Chem. –Eur. J. 2018, 24, 3862-3872. - A Triphenylamine-Naphthalenediimide-Fullerene Triad: Synthesis, Photoinduced Charge Separation and Solution-Processable Bulk Heterojunction Solar Cells
Srivani, D.; Gupta, A.; Bhosale, S. V.; Ohkubo, K.; Bhosale, R. S.; Fukuzumi, S.; Bilic, A.; Jones, L. A.; Bhosale, S. V.
Asian J. Org. Chem. 2018, 7, 220-226. - Light-driven C-H Oxygenation of Methane into Methanol and Formic Acid by Molecular Oxygen Using a Perfluorinated Solvent
Ohkubo, K.; Hirose, K.
Angew. Chem. Int. Ed. 2018, 57, 2126-2129.
Selected as a Cover Picture
2017
- Inter- and Intramolecular Electron-Transfer Reduction Properties of Coronenediimide Derivatives via Photoinduced Processes
Yoshida, M.; Sakai, H.; Ohkubo, K.; Fukuzumi, S.; Hasobe, T.
J. Phys. Chem. C 2017, 122, 13333-13346. - Ionic Manipulation of Charge-transfer and Photodynamics of [60]Fullerene Confined in Pyrrolo-tetrathiafulvalene Cage
Bahring, S.; Larsen, K. R.; Supur, M.; Nielsen, K. A.; Poulsen, T.; Ohkubo, K.; Marlatt, C. W.; Miyazaki, E.; Takimiya, K.; Flood, A. H.; Fukuzumi, S.; Jeppesen, J. O.
Chem. Commun. 2017, 53, 9898-9901. - Multi-level Non-volatile Organic Transistor-based Memory Using Lithium-ion-encapsulated Fullerene as a Charge Trapping Layer
Tran, C. M.; Sakai, H.; Kawashima, Y.; Ohkubo, K.; Fukuzumi, S.; Murata, H.
Org. Electron. 2017, 45, 234-239. - Synthesis of Methylated Quercetin Analogues for Enhancement of Radical-scavenging Activity
Imai, K.; Nakanishi, I.; Ohkubo, K.; Ohba, Y.; Arai, T.; Mizuno, M.; Fukuzumi, S.; Matsumoto, K.; Fukuhara, K.
RSC Adv. 2017, 7, 17968-17979. - Dual Function Photocatalysis of Cyano-bridged Heteronuclear Metal Complexes for Water Oxidation and Two-electron Reduction of Dioxygen to Produce Hydrogen Peroxide as a Solar Fuel
Aratani, Y.; Suenobu, T.; Ohkubo, K.; Yamada, Y.; Fukuzumi, S.
Chem. Commun. 2017, 53, 3473–3476. - Thermodynamics and Photodynamics of a Monoprotonated Porphyrin Directly Stabilized by Hydrogen Bonding with Polar Protic Solvents
Suzuki, W.; Kotani, H.; Ishizuka, T.; Ohkubo, K.; Shiota, Y.; Yoshizawa, K.; Fukuzumi, S.; Kojima, T.
Chem.–Eur. J. 2017, 23, 4669–4679. - Selective CO Production in Photoelectrochemical Reduction of CO2 with a Cobalt Chlorin Complex Adsorbed on Multi-Walled Carbon Nanotubes in Water
Aoi, S.; Mase, K.; Ohkubo, K.; Suenobu, T.; Fukuzumi, S.
ACS Energy Lett. 2017, 2, 4077–4080. - Dihydroxylation of Styrene by Sodium Chlorite with Scandium Triflate
Ohkubo, K.; Hirose, K.; Shibata, T.; Takamori, K.; Fukuzumi, S.
J. Phys. Org. Chem. 2017, 30, e3619. - Exfoliation and Supramolecular Functionalization of Graphene with an Electron Donor Perylenediimide Derivative
Martín-Gomis, L.; Karousis, N.; Fernández-Lázaro, F.; Petsalakis, I. D.; Ohkubo, K.; Fukuzumi, S.; Tagmatarchis N. Sastre-Santos, Á.
Photochem. Photobiol. Sci. 2017, 16, 596–605. - Impact of Peripheral Substituents in Regioselective Synthesis of Position-10 or Position-20 Bromobacteriochlorins
Joshi, P.; Ohkubo, K.; Dukh, M.; Tabaczynski, W.; Patel, N. J.; Missert, J. R.; Fukuzumi, S.; Pandey, R. K.
Tetrahedron Lett. 2017, 58, 851–854. - Photoinduced Electron Transfer in 9-Substituted 10-Methylacridinium Ions
Tsudaka, T.; Kotani, H.; Ohkubo, K.; Nakagawa, T.; Tkachenko, N. V.; Lemmetyinen, H.; Fukuzumi, S.
Chem.–Eur. J. 2017, 23, 1306–1317.
2016
- Synthetic Control over Intra- and Intermolecular Charge Transfer Can Turn on the Fluorescence Emission of Non-emissive Coumarin
Jhun, B. H.; Ohkubo, K.; Fukuzumi, S.; You, Y.
J. Mater. Chem. C 2016, 4, 4556-4567. - Photooxygenation of Alkanes by Dioxygen with p-Benzoquinone Derivatives with High Quantum Yields
Ohkubo, K.; Hirose, K.; Fukuzumi, S.
Photochem. Photobiol. Sci. 2016, 8, 731-714. - Two-Phase Photocatalytic Oxidation of Toluene Derivatives by Dioxygen with 3-Cyano-1-decylquinolinium Ion
Ohkubo, K.; Hirose, K.; Fukuzumi, S.
RSC Adv. 2016, 6, 41011-41014. - Catalytic Reduction of Proton, Oxygen and Carbon Dioxide with Cobalt Macrocyclic Complexes
Mase, K.; Aoi, S.; Ohkubo, K.; Fukuzumi, S.
J. Porphyrins Phthalocyanines 2016, 20, 935-949. - Catalytic Hydroxylation of Benzene to Phenol by Dioxygen with an NADH Analog
Hirose, K.; Ohkubo, K.; Fukuzumi, S.
Chem.–Eur. J. 2016, 22, 12904-12909. - Solvent-Free Photooxidation of Alkanes by Dioxygen with 2,3-Dichloro-5,6-dicyano-p-benzoquinone via Photoinduced Electron Transfer
Ohkubo, K.; Hirose, K.; Fukuzumi, S.
Chem.–Asian. J. 2016, 11, 2255-2259. - Axially Substituted Silicon Phthalocyanine as Electron Donor in a Dyad and Triad with Azafullerene as Electron Acceptor for Photoinduced Charge Separation
Rotas, G.; Martín-Gomis, L.; Ohkubo, K.; Fernández-Lázaro, F.; Fukuzumi, S.; Tagmatarchis, N.; Sastre-Santos, Á.
Chem.–Eur. J. 2016, 22, 15137-15143. - Reactivity of 2,2-Diphenyl-1-picrylhydrzyl Solubilized in Water by β-Cyclodextrin and Its Methylated Derivative
Nakanishi, I.; Ohkubo, K.; Kamibayashi, M.; Ogawa, Y.; Ozawa, T.; Matsumoto, K.; Fukuzumi, S.
Chem. Select 2016, 1, 3367-3370. - Controllable Threshold Voltage in Organic Complementary Logic Circuits with an Electron-Trapping Polymer and Photoactive Gate Dielectric Layer
Dao, T. T.; Sakai, H.; Nguyen, H. T.; Ohkubo, K.; Fukuzumi, S.; Murata, H.
ACS Appl. Mater. Interfaces 2016, 8, 18249-18255. - Synthetically Tuneable Biomimetic Artificial Photosynthetic Reaction Centres That Closely Resemble the Natural System in Purple Bacteria
Lee, S.-H.; Blake, I. M.; Larsen, A. G.; McDonald, J. A.; Ohkubo, K.; Fukuzumi, S.; Reimers, J. R.; Crossley, M. J.
Chem. Sci. 2016, 7, 6534-6550. - Photocatalytic Oxidation of Iron(II) Complexes by Dioxygen with 9-Mesityl-10-methylacridinium Ion
Tsudaka, T.; Ohkubo, K.; Fukuzumi, S.
Chem. Commun. 2016, 52, 6178-6180. - Photoinduced Electron Transfer in Porous Organic Salt Crystals Impregnated with Fullerenes
Hasegawa, T.; Ohkubo, K.; Hisaki, I.; Miyata, M.; Tohnai, N.; Fukuzumi, S.
Chem. Commun. 2016, 52, 7928-7931. - Aluminium Ion-Promoted Radical-Scavenging Reaction of Methylated Hydroquinone Derivatives
Nakanishi, I.; Ohkubo, K.; Ogawa, Y.; Matsumoto, K.; Ozawa, T.; Fukuzumi, S.
Org. Biomol. Chem. 2016, 14, 7956-7961. - Electrochemical Reduction of Cationic Li+@C60 to Neutral Li+@C60•–: Isolation and Characterisation of Endohedral [60]Fulleride
Ueno, H.; Aoyagi, S.; Yamazaki, Y.; Ohkubo, K.; Ikuma, N.; Okada, H.; Kato, T.; Matsuo, Y.; Fukuzumi, S.; Kokubo, K.
Chem. Sci. 2016, 7, 5770-5774. - A Profluorescent Nitroxide Probe for Ascorbic Acid Detection and Its Application to Quantitative Analysis of Diabetic Rat Plasma
Matsuoka, Y.; Ohkubo, K.; Yamasaki, T.; Yamato, M.; Ohtabu, H.; Shirouzu, T.; Fukuzumi, S.; Yamada, K.
RSC. Adv. 2016, 6, 60907-60915. - Photocatalytic Reduction of CO2 and H2O to CO and H2 with a Cobalt Chlorin Complex Adsorbed on Multi-Walled Carbon Nanotubes
Aoi, S.; Mase, K.; Ohkubo, K.; Fukuzumi, S.
Catal. Sci. Technol. 2016, 6, 4077-4080. - Aromatic Monochlorination Photosensitized by DDQ with Hydrogen Chloride under Visible Light Irradiation
Ohkubo, K.; Fujimoto, A.; Fukuzumi, S.
Chem.–Asian J. 2016, 11, 996-999. - Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine
Jung, J.; Neu, H. M.; Leeladee, P.; Siegler, M. A.; Ohkubo, K.; Goldberg, D. P.; Fukuzumi, S.
Inorg. Chem. 2016, 55, 3218-3228. - Much Enhanced Electron-Transfer Reactivity of a Nonheme Iron(IV)-Imido Complex as Compared to the Iron(IV)-Oxo Analog
Vardhaman, A. K.; Lee, Y.-M.; Jung, J.; Ohkubo, K.; Nam, W.; Fukuzumi, S.
Angew. Chem., Int. Ed. 2016, 55, 3709-3713. - Photoinduced Processes of Supramolecular Nanoarrays Composed of Porphyrin and Benzo[ghi]perylenetriimide Units through Triple Hydrogen Bonds with One-Dimensional Columnar Phases
Sakai, H.; Ohkubo, K.; Fukuzumi, S.; Hasobe, T.
Chem.–Asian J. 2016, 11, 613-624. - The Effect of Metallation on Porphyrin-Based Bifunctional Agents in Tumor-Imaging and Photodynamic Therapy
Patel, N. J.; Chen, Y.; Joshi, P.; Pera, P.; Baumann, H.; Missert, J. R.; Ohkubo, K.; Fukuzumi, S.; Nani, R. R.; Schnermann, M. J.; Chen, P.; Zhu, J.; Kadish, K. M.; Pandey, R. K.
Bioconjugate Chem. 2016, 27, 667-680. - An Amphoretic Reactivity of a Mixed-Valent Bis(μ-oxo)dimanganese(III,IV) Complex Acting as an Electrophile and a Nucleophile
Sankaralingam, M.; Jeon, S. H.; Lee, Y.-L.; Seo, M. S.; Ohkubo, K.; Fukuzumi, S.; Nam, W.
Dalton Trans. 2016, 45, 376-383.
2015
- Multiple Photosynthetic Reaction Centres of Porphyrinic Polypeptide-Li+@C60 Supramolecular Complexes
Ohkubo, K.; Hasegawa, T.; Rein, R.; Solladié, N.; Fukuzumi, S.
Chem. Commun. 2015, 51, 17517-17520. - Cyclic Tetramers of Zinc Chlorophylls as a Coupled Light-Harvesting Antenna–Charge Separation System
Shinozaki, Y.; Ohkubo, K.; Fukuzumi, S.; Sugawa, K.; Otsuki, J.
Chem.–Eur. J. 2015, 22, 1165-1176. - Long-Lived Photoinduced Charge Separation in Inclusion Complexes Composed of a Phenothiazine-Bridged Cyclic Porphyrin Dimer and Fullerenes
Kamimura, T.; Ohkubo, K.; Kawashima, Y.; Ozaki, S.; Sakaguchi, K.; Fukuzumi, S.; Tani, F.
J. Phys. Chem. C 2015, 119, 25634-25650. - Laser-Induced Dynamics of Peroxo-Dicopper(II) Complexes Vary with Ligand Architecture; One-Photon Two-Electron O2-Ejection and Formation of Mixed-Valent CuICuII-Superoxide Intermediates
Saracini, C.; Ohkubo, K.; Suenobu, T.;, Meyer, G. J.; Karlin, K. D.; Fukuzumi, S.
J. Am. Chem. Soc. 2015, 137, 15865-15874. - Efficient Singlet Oxygen Generation from Sugar Pendant C60 Derivatives for Photodynamic Therapy
Yano, S.; Naemura, M.; Toshimitsu, A.; Akiyama, M.; Ikeda, A.; Kikuchi, J.; Shen, X.; Duan, Q.; Narumi, A.; Inoue, M.; Ohkubo, K.; Fukuzum, S.
Chem. Commun. 2015, 51, 16605-16608. - Effect of Alkyl Group on Transnitrosation of N-Nitrosothiazolidine Thiocarboxamides Article Type: Full Length Article
Inami, K.; Ono, Y.; Kondo, S.; Nakanishi, I.; Ohkubo, K.; Fukuzumi, S.; Mochizuki, M.
Bioorg. Med. Chem. 2015, 23, 6733-6739. - Activationless Electron Self-Exchange of High-Valent Oxo and Imido Complexes of Chromium Corroles
Liu, S.; Jung, J.; Ohkubo, K.; Hicks, S. D.; Bougher, C. J.; Abu-Omar, M. M.; Fukuzumi, S.
Inorg. Chem. 2015, 54, 9223-9228. - Mechanism of a One-Photon Two-Electron Process in Photocatalytic Hydrogen Evolution from Ascorbic Acid with a Cobalt Chlorin Complex
Aoi, S.; Mase, K.; Ohkubo, K.; Fukuzumi, S.
Chem. Commun. 2015, 51, 15145-15148. - Catalytic Two-Electron Reduction of Dioxygen Catalysed by Metal-Free [14]Triphyrin(2.1.1)
Mase, K.; Ohkubo, K.; Xue, Z.; Yamada, H.; Fukuzumi, S.
Chem. Sci. 2015, 6, 6496-6504. - Formation of Ground State Triplet Diradicals from Annulated Rosarin Derivatives by Triprotonation
Fukuzumi, S.; Ohkubo, K.; Ishida, M.; Preihs, C.; Chen, B.; Borden, W. Kim, D.; Sessler, J. L.
J. Am. Chem. Soc. 2015, 137, 9780-9783. - Modulation of Energy Conversion Processes in Carbonaceous Molecular Bearings
Hitosugi, S.; Ohkubo, K.; Kawashima, Y.; Matsuno, T.; Kamata, S.; Nakamura, K.; Kono, H.; Sato, S.; Fukuzumi, S.; Isobe, H.
Chem. Asian J. 2015, 10, 2404-2410. - On-Off Switch of Charge-Separated States of Pyridine-Vinylene-Linked Porphyrin-C60 Conjugates Detected by EPR
Kirner, S. V.; Henkel, C.; Margraf, J. T.; Ohkubo, K.; Echegoyen, L.; Fukuzumi, S.; Clark, T.; Gildi, D. M.
Chem. Sci. 2015, 6, 5994-6007. - Metal-free Hydrogen Evolution with Nanoparticles Derived from Pyrene via Two-photon Ionization Induced by Laser Irradiation
Ohkubo, K.; Kohno, N.; Yamada, Y.; Fukuzumi, S.
Chem. Commun. 2015, 51, 11515-11518. - Energy Migration within Hexameric Hemoprotein Reconstituted with Zn Porphyrinoid Molecules
Oohora, K.; Mashima, T.; Ohkubo, K.; Fukuzumi, S.; Hayashi, T.
Chem. Commun. 2015, 51, 11138-11140. - Broadband Light Harvesting and Fast Charge Separation in Ordered Self-Assemblies of Electron Donor-Acceptor-Functionalized Graphene Oxide Layers for Effective Solar Energy Conversion
Supur, M.; Kawashima, Y.; Mase, K.; Ohkubo, K.; Hasobe, T.; Fukuzumi, S.
J. Phys. Chem. C 2015, 119, 13488-13495. - Efficient Epoxidation of Styrene Derivatives by a Nonheme Iron(IV)-oxo Complex via Proton-Coupled Electron Transfer with Triflic Acid
Park, J.; Lee, Y.-M.; Ohkubo, K.; Nam, W.; Fukuzumi, S.
Inorg. Chem. 2015, 54, 5806-5812. - Selective Electrochemical Reduction of CO2 to CO with a Cobalt Chlorin Complex Adsorbed on Multi-Walled Carbon Nanotubes in Water
Aoi, S.; Mase, K.; Ohkubo, K.; Fukuzumi, S.
Chem. Commun. 2015, 51, 10226-10228. - Graphene Oxide-Li+@C60 Donor-Acceptor Composite for Photoenergy Conversion
Supur, M.; Kawashima, Y.; Ohkubo, K.; Sakai, H.; Hasobe, T.; Fukuzumi, S.
Phys. Chem. Chem. Phys. 2015, 17, 15732-15738. - Coronenetetraimide-Centered Cruciform Pentamers Containing Multiporphyrin Units: Synthesis and Sequential Photoinduced Energy and Electron Transfer Dynamics
Hasobe, T.; Ida, K.; Sakai, H.; Ohkubo, K.; Fukuzumi, S.
Chem.–Eur. J. 2015, 21, 11196-11205. - Size-selective Incorporation of Donor-Acceptor Linked Dyad Cations into Zeolite Y and Long-Lived Charge Separation
Fukuzumi, S.; Itoh, A.; Ohkubo, K.; Suenobu, T.
RSC Adv. 2015, 5, 45582-45585. - Photoinduced Electron Transfer in a Supramolecular Triad Produced by Porphyrin Anion-Induced Electron Transfer from Tetrathiafulvalene Calix[4]pyrrole to Li+@C60
Davis, C. M.; Ohkubo, K.; Lammer, A. D.; Kim, D. S.; Kawashima, Y.; Sessler, J. L.; Fukuzumi, S.
Chem. Commun. 2015, 51, 9789-9792. - Enzyme Repurposing of a Hydrolase as an Emergent Peroxidase upon Metal Binding
Fujieda, N.; Schätti, J.; Stuttfeld, E.; Ohkubo, K.; Maier, T.; Fukuzumi, S.; Ward, T. R.
Chem. Sci. 2015, 6, 4060-4065. - A Simple Zinc-Porphyrin-NDI Dyad System Generates a Light Energy to Proton Potential Across a Lipid Membrane
Kelspn, M. M. A.; Ohkubo, K.; Jones, L. A.; Jackson, S. L.; Bhosale, S. V.; Gupta, A.; Fukuzumi, S.; Bhosale, S. V.
Dyes Pigments 2015, 120, 340-346. - Tetrapheneylethene-based Star Shaped Porphyrins: Synthesis, Self-assembly, Optical and Photophysical Study
Rananaware, A.; Bhosale, R. S.; Ohkubo, K.; Patil, H.; Jones, L. A.; Jackson, S. L.; Fukuzumi, S.; Bhosale, S. V.; Bhosale, S. V.
J. Org. Chem. 2015, 80, 3832-3840. - Solubilisation of a 2,2-Diphenyl-1-picrylhydrazyl Radical to Water by β-Cyclodextrin to Evaluate the Radical-Scavenging Activity of Antioxidants in Aqueous Media
Nakanishi, I.; Ohkubo, K.; Imai, K.; Kamibayashi, M.; Yoshihashi, Y.; Matsumoto, K.-i.; Fukuhara, K.; Terada, K.; Itoh, S.; Ozawa, T.; Fukuzumi, S.
Chem. Commun. 2015, 51, 8311-8314. - Light-Driven, Proton-Controlled, Catalytic Aerobic C-H Oxidation Mediated by a Mn(III) Porphyrinoid Complex
Neu, H.; Jung, J.; Baglia, R. A..; Siegler, M. A.; Ohkubo, K.; Fukuzumi, S. Goldberg, D. P.
J. Am. Chem. Soc. 2015, 137, 4614-4617. - Singlet Oxygen Generation from Li+@C60 Nano-Aggregates Dispersed by Laser Irradiation in Aqueous Solution
Ohkubo, K.; Kohno, N.; Yamada, Y.; Fukuzumi, S.
Chem. Commun. 2015, 51, 8082-8085. - Catalytic Two-Electron Reduction of Dioxygen by Ferrocene Derivatives with Manganese(V) Corroles
Jung, J.; Liu, S.; Ohkubo, K.; Abu-Omar, M. M.; Fukuzumi, S.
Inorg. Chem. 2015, 54, 4285-4291. - Near-Infrared-Induced Electron Transfer of an Uranyl Macrocyclic Complex without Energy Transfer to Dioxygen
Davis, C. M.; Ohkubo, K.; Ho, I.-T.; Zhang, Z.; Ishida, M.; Fang, Y.; Lynch, V. M.; Kadish, K. M.; Sessler, J. L.; Fukuzumi, S.
Chem. Commun. 2015, 51, 6757-6760. - Lewis Acid-Induced Change from Four- to Two-Electron Reduction of Dioxygen Catalyzed by Copper Complexes Using Scandium Triflate
Kakuda, S.; Rolle, C. J.; Ohkubo, K.; Siegler, M. A.; Karlin, K. D.; Fukuzumi, S.
J. Am. Chem. Soc. 2015, 137, 3330-3337. - Near-Infrared Photoelectrochemical Conversion via Photoinduced Charge Separation in Supramolecular Complexes of Anionic Phthalocyanines with Li+@C60
Kawashima, Y.; Ohkubo, K.; Blas-Ferrando, V. M.; Sakai, H.; Font-Sanchis, E.; Ortís, J.; Fernández-Lázaro, F.; Hasobe, T.; Sastre-Santos, Á.; Fukuzumi, S.
J. Phys. Chem. B 2015, 119, 7690-7697. - Does a Nitrogen Matter?: Synthesis and Photoinduced Electron Transfer of Perylenediimide Donors Covalently Linked to C59N and C60 Acceptors
Martín-Gomis, L.; Rotas, G.; Ohkubo, K.; Fernández-Lázaro, F.; Fukuzumi, S.; Tagmatarchis, N.; Sastre-Santos, Á.
Nanoscale 2015, 7, 7437-7444. - Nickel and Palladium Complexes of a Non-innocent β-Diketiminate Ligand Containing Phenol Groups
Morimoto, Y.; Takaichi, J.; Hanada, S.; Ohkubo, K.; Sugimoto, H.; Fujieda, N.; Fukuzumi, S.; Itoh, S.
J. Porphyrins Phthalocyanines 2015, 19, 377-387. - Much Enhanced Catalytic Reactivity of Cobalt Chlorin Derivatives on Two-Electron Reduction of Dioxygen to Produce Hydrogen Peroxide
Mase, K.; Ohkubo, K.; Fukuzumi, S.
Inorg. Chem. 2015, 54, 1808-1815. - Ultrafast Photoinduced Electron Transfer in Face-to-Face Charge-Transfer π-Complexes of Planar Porphyrins and Hexaazatriphenylene Derivatives
Aoki, T.; Sakai, H.; Ohkubo, K.; Sakanoue, T.; Takenobu, T.; Fukuzumi, S.; Hasobe, T.
Chem. Sci. 2015, 6, 1498-1509. - Mechanisms and Applications of Cyclometalated Pt(II) Complexes in Photoredox Catalytic Trifluoromethylation
Choi, W. J.; Choi, S.; Ohkubo, K.; Fukuzumi, S.; Cho, E. J.; You, Y.
Chem. Sci. 2015, 6, 1454-1464. - Solvent-Free One-Step Photochemical Hydroxylation of Benzene Derivatives by the Singlet Excited State of 2,3-Dichloro-5,6-dicyano-p-benzoquinone Acting as a Super Oxidant
Ohkubo, K.; Hirose, K.; Fukuzumi, S.
Chem.–Eur. J. 2015, 21, 2855-2861. - Synthesis and Photodynamics of Diphenylethylene-Bridged Porphyrin-Quinoidal Porphyrin Hybrids
Sakatani, S.; Kamimura, T.; Ohkubo, K.; Fukuzumi, S.; Tani, F.
J. Porphyrins Phthalocyanines 2015, 19, 219-232. - Photocatalytic H2 Evolution from NADH with Carbon Quantum Dots/Pt and 2-Phenyl-4-(1-naphthyl)quinolinium Ion
Wu, W.; Zhan, L.; Ohkubo, K.; Yamada, Y.; Wu, M.; Fukuzumi, S.
J. Photochem. Photobiol. B Biol. 2015, 152, 63-70. - Laser-Induced Pinpoint Hydrogen Evolution from Benzene and Water Using Metal Free Single-Walled Carbon Nanotubes with High Quantum Yields
Ohkubo, K.; Kohno, N.; Yamada, Y.; Fukuzumi, S.
Chem. Sci. 2015, 6, 666-674.
2014
- Long-Lived Charge Separation in a Rigid Pentiptycene Bis(crown ether)– Li+@C60 Host–Guest Complex
Supur, M.; Kawashima, Y.; Ma, Y.-X.; Ohkubo, K.; Chen, C.-F.; Fukuzumi, S.
Chem. Commun. 2014, 50, 15796-15798. - Formation of the Long-Lived Charge-Separated State of the 9-Mesityl-10-methylacridinium Cation Incorporated into Mesoporous Aluminosilicate at High Temperatures
Fukuzumi, S.; Itoh, A.; Suenobu, T.; Ohkubo, K.
J. Phys. Chem. C 2014, 118, 24188-24196. - Photoinduced Charge Separation in Ordered Self-Assemblies of Perylenediimide-Graphene Oxide Hybrid Layers
Supur, M.; Ohkubo, K.; Fukuzumi, S.
Chem. Commun. 2014, 50, 13359-13361. - Photoelectrochemical Properties of Supramolecular Composites of an Anionic Zinc Chlorin and Li+@C60 on SnO2
Ohkubo, K.; Kawashima, Y.; Mase, K.; Sakai, H.; Hasobe, T.; Fukuzumi, S.
J. Porphyrins Phthalocyanines 2014, 18, 982-990. - Photoinduced Electron Transfer in a Charge-Transfer Complex Formed between Corannulene and Li+@C60 by Concave-Convex p-p Interactions
Yamada, M.; Ohkubo, K.; Shionoya, M.; Fukuzumi
J. Am. Chem. Soc. 2014, 136, 13240–13248. - Electronic Infrared Light Absorption of Tri-palladium Complex Containing Two p-Expanded Tetracene Ligands
Suzuki, T.; Nakagawa, T.; Ohkubo, K.; Fukuzumi, S.; Matsuo, Y.
Chem. Sci. 2014, 5, 4888-4894. - Binding of Scandium Ions to Metalloporphyrin–Flavin Complexes for Long-Lived Charge Separation
Kojima, T.; Kobayashi, R.; Ishizuka, T.; Yamakawa, S.; Kotani, H.; Nakanishi, T.; Ohkubo, K.; Shiota, Y.; Yoshizawa, K.; Fukuzumi, S.
Chem.–Eur. J. 2014, 20, 15518-15532. - Supramolecular Formation of Lithium-Ion-Encapsulated PCBM Fullerene with Sulfonated meso-Tetraphenylporphyrins and Long-Lived Charge-Separation
Kawashima, Y.; Ohkubo, K.; Okada, H.; Matsuo, Y.; Fukuzumi, S.
ChemPhysChem 2014, 3782-3790. - Photocatalytic Oxygenation of 10-Methyl-9,10-dihydroacridine by O2 with Manganese Porphyrins
Jung, J.; Ohkubo, K.; Goldberg, D.; Fukuzumi, S.
J. Phys. Chem. A 2014, 118, 6223-6229. - Cyclo[8]pyrrole: An Androgynous Expanded Porphyrin that Acts as Both an Electron Donor and Acceptor in Anion-Bound Supramolecular Electron Transfer Complexes
Ohkubo, K.; Mase, K.; Karnas, E.; Sessler, J. L.; Fukuzumi, S.
J. Phys. Chem. C 2014, 118, 18436-18444. - Submillisecond-Lived Photoinduced Charge Separation in a Fully Conjugated Phthalocyanine-Perylenebenzimidazole Dyad
Blas-Ferrando, V. M.; Ortiz, J.; Ohkubo, K.; Fukuzumi, S.; Fernández-Lázaro, F.; Sastre-Santos, Á.
Chem Sci. 2014, 5, 4785-4793. - Robust Inclusion Complexes of Crown-ether-fused Tetrathiafulvalenes with Li+@C60 Affording Efficient Photodriven Charge Separation
Supur, M.; Kawashima, Y.; Larsen, K. R.; Ohkubo, K.; Jeppesen, J. O.; Fukuzumi, S.
Chem.–Eur. J. 2014, 20, 13976-13983. - Photoinduced Electron Transfer in a Dynamic Supramolecular System with Curved π-structures
Hitotsugi, S.; Ohkubo, K.; Iizuka, R.; Kawashima, Y.; Nakamura, K.; Sato, S.; Kono, H.; Fukuzumi, S.; Isobe, H.
Org. Lett. 2014, 16, 3352-3355. - Evaluation of the Sonosensitizing Activities of 5-Aminolevulinic Acid and Sn(IV) Chlorin e6 in the Tumor-bearing Chick Embryo
Uto, Y.; Tamatani, D.; Mizuki, Y.; Endo, Y.; Nakanishi, I.; Ohkubo, K.; Fukuzumi, S.; Ishizuka, M.; Tanaka, T.; Kuchiike, D.; Kubo, K.; Inui, T.; Hori, H.
Anticancer Res. 2014, 34, 4583-4588. - Photoinduced Electron Transfer from a Tetrathiafulvalene-Calix[4]pyrrole to a Porphyrin Carboxylate within a Supramolecular Ensemble
Davis, C. M.; Kawashima, Y.; Ohkubo, K.; Lim, J. M.; Kim, D.; Fukuzumi, S.; Sessler, J. L.
J. Phys. Chem. C 2014, 118, 13505-13513. - Control of Reaction Pathways in the Photochemical Reaction of a Quinone with Tetramethylethylene by Metal Binding
Yamamoto, H.; Ohkubo, K.; Akimoto, S.; Fukuzumi, S.; Tsuda, A.
Org. Biomol. Chem. 2014, 12, 7004-7017. - Long-Lived Charge-Separated States Produced in Supramolecular Complexes between Anionic and Cationic Porphyrins
Bill, N. L.; Ishida, M.; Kawashima, Y.; Ohkubo, K.; Sung, Y. M.; Lynch, V. M.; Lim, J. M.; Kim, D.; Sessler, J. L.; Fukuzumi, S.
Chem. Sci. 2014, 5, 3888-3896. - Mechanistic Insights into the Oxidation of Substituted Phenols via Hydrogen Atom Abstraction by a Cupric Superoxo Complex
Lee, J. Y.; Peterson, R. L.; Ohkubo, K.; Garcia-Bosch, I.; Himes, R. A.; Voertink, J.; Moore, C. D.; Solomon, E. I.; Fukuzumi, S.; Karlin, K. D.
J. Am. Chem. Soc. 2014, 136, 9925-9937. - Redox Chemistry of Nickel(II)-Complexes Supported by a Series of Non-innocent β-Diketiminate Ligands
Takaichi, J.; Morimoto, Y.; Ohkubo, K.; Shimokawa, C.; Hojo, T.; Mori, S.; Asahara, H.; Sugimoto, H.; Fujieda, N.; Nishiwaki, N.; Fukuzumi, S.; Itoh, S.
Inorg. Chem. 2014, 52, 6159-6169. - Sumanenetrione Anions Generated by Electrochemical and Chemical Reduction
Higashibayashi, S.; Shrestha, B. B.; Morita, Y.; Ehara, M.; Ohkubo, K.; Fukuzumi, S.; Sakurai, H.
Chem. Lett. 2014, 43, 1297-1299. - Enhancement of Ultraviolet Light Responsivity of a Pentacene Phototransistor by Introducing Photoactive Molecules into a Gate Dielectric
Dao, T.; Matsushima, T.; Murakami, M.; Ohkubo, K.; Fukuzumi, S.; Murata, H.
Jpn. J. Appl. Phys. 2014, 53, 02BB03/1-02BB03/5. - Electron-Transfer Reduction Properties and Excited-State Dynamics of Benzo[ghi]peryleneimide and Coroneneimide Derivatives
Ida, K.; Sakai, H.; Ohkubo, K.; Araki, Y.; Wada, T.; Sakanoue, T.; Takenobu, T.; Fukuzumi, S.; Hasobe, T.
J. Phys. Chem. C 2014, 118, 7710-7720. - Selective Interaction of Single-walled Carbon Nanotubes and Propylamine under Photoirradiation
Maeda, Y.; Hasuike, Y.; Ohkubo, K.; Tashiro, A.; Kaneko, S.; Yamada, M.; Hasegawa, T.; Akasaka, T.; Zhou, J.; Lu, J.; Nagase, S.; Fukuzumi, S.
ChemPhysChem 2014, 15, 1821-1826. - Bisdonor-azaBODIPY-Fullerene Supramolecules – Syntheses, Characterization and Light Induced Electron Transfer Studies
Bandi, V.; El-khouly, M. E.; Ohkubo, K.; Nesterov, V. N. Zandler, M. E.; Fukuzumi, S.; D’Souza, F.
J. Phys. Chem. C 2014, 118, 2321-2332. - Photoinduced Electron Transfer in a Supramolecular Nanohybrid Between a Carbon Nanohorn with an NH3+ Moiety and C60 with a Crown Ether Moiety
Vizuete, M.; Gómez-Escalonilla, M. J.; Fierro, J. L. G.; Ohkubo, K.; Fukuzumi, S.; Yudasaka, M.; Iijima, S.; Nierengarten, J.-F.; Langa, F.
Chem. Sci. 2014, 5, 2072-2080. - Highly Efficient Cycloreversion of Photochromic Dithienylethene Compounds Using Visible Light-Driven Photoredox Catalysis
Lee, S.; You, Y.; Ohkubo, K.; Fukuzumi, S.; Nam, W.
Chem. Sci. 2014, 5, 1463-1474. - Macrocyclic Dyads Based on C60 and Perylenediimides Connected via Click Chemistry
Pla, S.; Martín-Gomis, L.; Ohkubo, K.; Fukuzumi, S.; Fernández-Lazaro, F.; Sastre-Santos, Á.
Asian J. Org. Chem. 2014, 3, 185-197. - Disproportionation of 2,2-Diphenyl-1-Picrylhydrazyl Radical as a Model of Reactive Oxygen Species Catalysed by Lewis and/or Brønsted Acids
Nakanishi, I.; Kawashima, T.; Ohkubo, K.; Waki, T.; Uto, Y.; Kamada, T.; Ozawa, T.; Matsumoto, K.; Fukuzumi, S.
Chem. Commun. 2014, 50, 814-816.
2013
- Photochemical Oxidation of a Manganese(III) Complex with Oxygen and Toluene Derivatives to Form a Manganese(V)-oxo Complex
Jung. J.; Ohkubo, K.; Prokop-Prigge, K.; Neu, H.; Goldberg, D.; Fukuzumi, S.
Inorg. Chem. 2013, 52, 13594-13604. - Photocatalytic Monofluorination of Benzene by Fluoride via Photoinduced Electron Transfer with 3-Cyano-1-Methylquinolinium
Ohkubo, K.; Fujimoto, A.; Fukuzumi, S.
J. Phys. Chem. A 2013, 117, 10719-10725. - Electron Transfer in a Supramolecular Complex of Zinc Chlorin Carboxylate Anion with Li+@C60 Affording the Long-Lived Charge-Separated State
Kawashima, Y.; Ohkubo, K.; Mase, K.; Fukuzumi, S.
J. Phys. Chem. C 2013, 117, 21166-21177. - Tetrathiafulvalene-Annulated [28]Hexaphyrin(1.1.1.1.1.1): A Multi-electron Donor System Subject to Conformational Control
Jana, A.; Ishida, M.; Cho, K.; Ghosh, S. K.; Kwak, K.; Ohkubo, K.; Sung, Y. M.; Davis, C. M.; Lynch, V. M.; Lee, D.; Fukuzumi, S.; Kim, D.; Sessler, J. L.
Chem. Commun. 2013, 49, 8937-8939. - Small Reorganization Energies of Photoinduced Electron Transfer between Spherical Fullerenes
Kawashima, Y.; Ohkubo, K.; Fukuzumi, S.
J. Phys. Chem. A 2013, 117, 6737-6743. - A ‘Two-Point’ Bound Zinc Porphyrin-Zinc Phthalocyanine-Fullerene Supramolecular Triad for Sequential Energy and Electron Transfer
Kc, C. B.; Ohkubo, K.; Fukuzumi, S.; D’Souza, F.
Chem. Commun. 2013, 49, 7614-7616. - Ionic Conductivity of [Li+@C60](PF-) in Organic Solvents and Its Electrochemical Reduction to Li+@C60•–
Ueno, H.; Kokubo, K.; Nakamura, Y.; Ohkubo, K.; Ikuma, N.; Moriyama, H.; Fukuzumi, S.; Oshima, T.
Chem. Commun. 2013, 49, 7376-7378. - Porphyrins Fused with Strongly Electron Donating 1,3-Dithole-2-ylidene Moieties. Redox Control by Metal Cation Complexation and Anion Binding
Bill, N. L.; Ishida, M.; Bähring, S.; Lim, J. M.; Lee, S.; Davis, C. M.; Lynch, V. M.; Nielsen, K. A.; Jeppesen, J. O.; Ohkubo, K.; Fukuzumi, S.; Kim, D.; Sessler, J. L.
J. Am. Chem. Soc. 2013, 135, 10852-10862. - Photosynthetic Antenna-Reaction Center Mimicry with a Covalently Linked Monostyryl Boron Dipyrromethene-Aza Boron Dipyrromethene-C60 Triad
Shi, W.-J.; El-Khouly, M. E.; Ohkubo, K.; Fukuzumi, S.; Ng, D. K.
Chem.-Eur. J. 2013, 19, 11332-11341. - η5-Cyclopentadienyl-Iron(II)-[14]Triphyrin(2.1.1) Sandwich Compounds: Synthesis, Characterization, and Stable Redox Interconversion
Xue, Z.; Kuzuhara, D.; Ikeda, S.; Sakakibara, Y.; Ohkubo, K.; Aratani, N.; Okujima, T.; Uno, H.; Fukuzumi, S.; Yamada, H.
Angew. Chem., Int. Ed. 2013, 52, 7306-7309. - Acetate Induced Enhancement of Photocatalytic Hydrogen Peroxide Production from Oxalic Acid and Dioxygen
Yamada, Y.; Nomura, A.; Miyahigashi, T.; Ohkubo, K.; Fukuzumi, S.
J. Phys. Chem. A 2013, 117, 3751-3760. - Helicity Selective Photoreaction of Single-walled Carbon Nanotubes with Organosulfur Compounds in the Presence of Oxygen
Maeda, Y.; Higo, J.; Amagai, Y.; Matsui, J.; Ohkubo, K.; Yoshigoe, Y.; Hashimoto, M.; Eguchi, K.; Yamada, M.; Hasegawa, T.; Sato, Y.; Zhou, J.; Lu, J.; Miyashita, T.; Fukuzumi, S.; Murakami, T.; Tohji, K.; Nagase, S.; Akasaka, T.
J. Am. Chem. Soc. 2013, 135, 6356-6362. - Visible-Light-Induced Oxygenation of Benzene by the Triplet Excited State of 2,3-Dichloro-5,6-dicyano-p-benzoquinone
Ohkubo, K.; Fujimoto, A.; Fukuzumi, S.
J. Am. Chem. Soc. 2013, 135, 5368-5371.
Highlighted in ChemistryViews (Wiley-VCH) - Enhanced Photoelectrochemical Performance of Composite Photovoltaic Cells of Li+@C60-Sulphonated Porphyrin Supramolecular Nanoclusters
Ohkubo, K.; Kawashima, Y.; Sakai, H.; Hasobe, T.; Fukuzumi, S.
Chem. Commun. 2013, 49, 4474-4476. - Enhanced Catalytic Four-Electron Dioxygen (O2) and Two-Electron Hydrogen Peroxide (H2O2) Reduction with a Copper(II) Complex Possessing a Pendant Ligand Pivalamido Group
Kakuda, S.; Peterson, R. L.; Ohkubo, K.; Karlin, K. D.; Fukuzumi, S.
J. Am. Chem. Soc. 2013, 135, 6513-6522. - The Long-lived Electron Transfer State of 2-Phenyl-4-(1-naphthyl)quinolinium Ion Incorporated into Nanosized Mesoporous Silica-alumina Acting as a Robust Photocatalyst in Water
Yamada, Y.; Nomura, A.; Ohkubo, K.; Suenobu, T.; Fukuzumi, S.
Chem. Commun. 2013, 49, 5132-5134. - Excitation Wavelength Dependent Ultrafast Photoinduced Electron Transfer in Bisferrocene-BF2 Chelated Azadipyrromethene-Fullerene Tetrads
Bandi, V.; El-Khouly, M. E.; Ohkubo, K.; Nesterov, V. N.; Zandler, M. E.; Fukuzumi, S.; D’Souza, F.
Chem.-Eur. J. 2013, 19, 7221-7230. - Acid-Induced Mechanism Change and Overpotential Decrease in Dioxygen Reduction Catalysis with a Dinuclear Copper Complex
Das, D.; Lee, Y.-M.; Ohkubo, K.; Nam, W.; Karlin, K. D.; Fukuzumi, S.
J. Am. Chem. Soc. 2013, 135, 4018-4026. - A Broad-Band Capturing and Emitting Molecular Triad: Synthesis and Photochemistry
Bandi, V.; Ohkubo, K.; Fukuzumi, S.; D’Souza, F.
Chem. Commun. 2013, 49, 2867-2869. - Remarkable Enhancement of Photocatalytic Hydrogen Evolution Efficiency Utilizing An Internal Cavity of Supramolecular Porphyrin Hexagonal Nanocylinders Under Visible-Light Irradiation
Hasobe, T.; Sakai, H.; Mase, K.; Ohkubo, K.; Fukuzumi, S.
J. Phys. Chem. C 2013, 117, 4441-4449. - Comparison of Antioxidative Parameters for Eleven Food Factors in Terms of Anti-apoptotic Activity under X-ray Irradiation
Indo, H. P.; Nakanishi, I.; Ohkubo, K.; Yen, H.-C.; Nyui, M.; Manda, S.; Matsumoto, K.; Fukuhara, K.; Anzai, K.; Ikota, N.; Matsui, H.; Minamiyama, Y.; Nakajima, A.; Ichikawa, H.; Fukuzumi, S.; Ozawa, T.; Mukai, C.; Majima, H. J.
RSC Adv. 2013, 3, 4535-4538. - Decorating Single Layer Graphene Oxide with Electron Donor and Acceptor Molecules for Study of Photoinduced Electron Transfer
Das, S. K.; Bikram K. C., C.; Ohkubo, K.; Yamada, Y.; Fukuzumi, S.; D’Souza, F.
Chem. Commun. 2013, 49, 2013-2015. - Temperature Independent Catalytic Two-Electron Reduction of Dioxygen by Ferrocenes with a Tris[2-(2-pyridyl)ethyl]amine-Copper(II) Catalyst in the Presence of Perchloric Acid
Das, D.; Lee, Y.-M.; Ohkubo, K.; Nam, W.; Karlin, K. D.; Fukuzumi, S.
J. Am. Chem. Soc. 2013, 135, 2825-2834. - Efficient Two-Electron Reduction of Dioxygen to Hydrogen Peroxide with One-Electron Reductants with a Small Overpotential Catalyzed by a Cobalt Chlorin Complex
Mase, K.; Ohkubo, K.; Fukuzumi, S.
J. Am. Chem. Soc. 2013, 135, 2800-2808. - Submillisecond-lived Photoinduced Charge Separation in Inclusion Complexes Composed of Li+@C60 and Cyclic Porphyrin Dimers
Kamimura, T.; Ohkubo, K.; Kawashima, Y.; Nobukuni, H.; Naruta, Y.; Tani, F.; Fukuzumi, S.
Chem. Sci. 2013, 4, 1451-1461. - Oxygenation and Chlorination of Aromatic Hydrocarbons with Hydrochloric Acid Photosensitized by 9-Mesityl-10-methylacridinium Under Visible Light Irradiation
Ohkubo, K.; Mizushima, K.; Fukuzumi, S.
Res. Chem. Intermed. 2013, 39, 205-220. - Electrochemical Synthesis of Transparent, Amorphous C60-Rich Photoactive Low Doped Film with Interconnected Structure
Li, M.; Ishihara, S.; Ohkubo, K.; Liao, M.; Ji. Q.; Gu, C.; Yamauchi, Y.; Fukuzumi, S.; Ariga, K.
Small 2013, 8, 2064-2068. - Protonation-coupled Redox Reactions in Planar Antiaromatic meso-Pentafluorophenyl-substituted o-Phenylene Bridged Annulated Rosarins
Ishida, M.; Kim, S.-J.; Preihs, C.; Ohkubo, K.; Lim, J. M.; Lee, B. S.; Park, J. S.; Lynch, V. M. Roznyatovskiy, V. V.; Panda, P. K.; Lee, C.-H.; Fukuzumi, S.; Kim, D.; Sessler, J. L.
Nature Chem. 2013, 5, 15-20.
Selected as a Front Cover - Copper Complexes of Non-innocent β-Diketiminate Ligand Containing Phenol Groups
Takaichi, J.; Ohkubo, K.; Sugimoto, H.; Nakano, M.; Usa, D.; Maekawa, H.; Fujieda, N.; Nishiwaki, N.; Fukuzumi, S.; Itoh, S.
Dalton Trans. 2013, 42, 2438-2444.
2012
- Synthesis, Photophysical and Electrochemistry of Near-IR Absorbing Bacteriochlorins Related to Bacteriochlorophyll a
Kozyrev, A.; Ethirajan, M.; Chen, P.; Ohkubo, K.; Robinson, B. C.; Barkigia, K.; Fukuzumi, S.; Kadish, K. M.; Pandey, R. K.
J. Org. Chem. 2012, 77, 10260-10271. - 249. Photoelectrocatalysis Greatly Improves Cycloreversion Quantum Yields of Photochromic Dithienylethene Compounds
Lee, S.; You, Y.; Ohkubo, K.; Fukuzumi, S.; Nam, W.
Angew. Chem., Int. Ed. 2012, 51, 13154-13158. - High Stability of the Intermediates Radicals Enhances the Radical-Scavenging Activity of the Aminochromanols
Inami, K.; Nakanishi, I.; Morita, M.; Furukawa, M.; Ohkubo, K.; Fukuzumi, S.; Mochizuki, M.
RSC Adv. 2012, 2, 12714-12717. - Electronic Properties of Trifluoromethylated Corannulenes
Schmidt, B. M.; Seki, S.; Topolinski, B.; Ohkubo, K.; Fukuzumi, S.; Sakurai, H.; Dieter, L.
Angew. Chem. Int. Ed. 2012, 51, 10260-10271. - Ultrafast Charge Separation in Supramolecular Tetrapyrrole-Graphene Hybrids
Bikram, K. C.; Das, S.; Ohkubo, K.; Fukuzumi, S.; D’Souza, F. D.
Chem. Commun. 2012, 48, 11859-11861. - Electroreduction and Acid-Base Properties of Dipyrrolylquinoxalines
Fu, Z.; Zhang, M.; Zhu, W.; Karnas, E.; Mase, K.; Ohkubo, K.; Sessler, J. L.; Fukuzumi, S.; Kadish, K. M.
J. Phys. Chem. A 2012, 116, 10063-10073. - Zinc PhthalocyanineGraphene Hybrid Material for Energy Conversion: Synthesis, Characterization, Photophysics and Photoelectrochemical Cell Preparation
Karousis, N.; Oritz, J.; Ohkubo, K.; Hasobe, T.; Fukuzumi, S.; Sastre-Santos, Á.
J. Phys. Chem. C 2012, 116, 20564-20573. - Active Site Models for the CuA Site of PHM and DβM
Kunishita, A.; Ertem, M. Z.; Okubo, Y.; Tano, T.; Sugimoto, H.; Ohkubo, K.; Fujieda, N.; Fukuzumi, S.; Cramer, C. J.; Itoh, S.
Inorg. Chem. 2012, 51, 9465-9480. - Enhanced Photoinduced Electron-Transfer Reduction of Li+@C60 in Comparison with C60
Kawashima, Y.; Ohkubo, K.; Fukuzumi, S.
J. Phys. Chem. A 2012, 116, 8942-8948. - Photocatalytic Hydrogen Evolution from Carbon-neutral Oxalate with 2-Phenyl-4-(1-naphthyl)quinolinium Ion and Metal Nanoparticles
Yamada, Y.; Miyahigashi, T.; Ohkubo, K.; Fukuzumi, S.
Phys. Chem. Chem. Phys. 2012, 14, 10564-10571. - Catalytic Four-Electron Reduction of Dioxygen via Rate-Determining Proton-Coupled Electron Transfer to a Dinuclear Cobalt-μ-1,2-Peroxo Complex
Fukuzumi, S.; Mandal, S.; Mase, K.; Ohkubo, K.; Park, H.; Benet-Buchholz, J.; Nam, W.; Llobet, A.
J. Am. Chem. Soc. 2012, 134, 9906-9909. - Photochemical Properties of a Myoglobin-CdTe Quantum Dot Conjugate
Onoda, A.; Himiyama, T.; Ohkubo, K.; Fukuzumi, S.; Hayashi, T.
Chem. Commun. 2012, 48, 8054-8056.
Selected as an Inside Front Cover - Supramolecular Electron Transfer by Anion Binding
Fukuzumi, S.; Ohkubo, K.; D’Souza, F. D.; Sessler, J. L.
Chem. Commun. 2012, 48, 9801-9815.
Selected as a Front Cover - Improvement of Durability of an Organic Photocatalyst in p-Xylene Oxygenation by Addition of a Cu(II) Complex
Yamada, Y.; Maeda, K.; Ohkubo, K.; Karlin, K. D.; Fukuzumi, S.
Phys. Chem. Chem. Phys. 2012, 14, 9654-9659. - Chlorine Atom Substitution Influences Radical Scavenging Activity of 6-Chromanol
Inami, K.; Iizuka, Y.; Furukawa, M.; Nakanishi, I.; Ohkubo, K.; Fukuhara, K.; Fukuzumi, S.; Mochizuki, M.
Bioorg. Med. Chem. 2012, 20, 4049-4055. - Kinetics and Mechanism for the Scavenging Reaction of the 2,2-Diphenyl-1-picrylhydrazyl Radical by Synthetic Artepillin C Analogues
Kawashima, T.; Sushma, M.; Uto, Y.; Ohkubo, K.; Hori, H.; Matsumoto, K.; Fukuhara, K.; Ikota, N.; Fukuzumi, S.; Ozawa, T.; Anzai, K.; Nakanishi, I.
Bull. Chem. Soc. Jpn. 2012, 85, 877-883. - Rational Design of a Phthalocyanine-Perylenediimide Dyad with Long-Lived Charge-Separated State
Blas-Ferrando, V. M.; Ortiz, J.; Bouissane, L.; Ohkubo, K.; Fukuzumi, S.; Fernández-Lázaro, F.; Sastre-Santos, Á.
Chem. Commun. 2012, 48, 6241-6243. - Mechanism and Fluorescence Application of Electrochromism in Photochromic Dithienylcyclopentene
Lee, S.; You, Y.; Ohkubo, K.; Fukuzumi, S.; Nam, W.
Org. Lett. 2012, 14, 2238-2241. - Decoupling the Artificial Special Pair to Slow Down the Rate of Singlet Energy Transfer
Harvey, P. D.; Langlois, A.; Filatov, M.; Fortin, D.; Ohkubo, K.; Fukuzumi, S.; Guilard, R.
J. Porphyrins Phthalocyanines 2012, 16, 685-694. - Fluorescent Zinc Sensor with Minimized Proton-Induced Interferences: Photophysical Mechanism for Fluorescence Turn-On Response and Detection of Endogenous Free Zinc Ions
Kwon, J. E.; Lee, S.; You, Y.; Baek, K.-H.; Ohkubo, K.; Cho, J.; Fukuzumi, S.; Shin, I.; Park, S. Y.; Nam, W.
Inorg. Chem. 2012, 51, 8760-8774. - Remarkable Enhancement of Catalytic Activity of a 2:1 Complex between a Non-Planar Mo(V)-Porphyrin and a Ruthenium-Substituted Keggin-Type Heteropolyoxometalate in Catalytic Oxidation of Benzyl Alcohols
Yokoyama, A.; Miyazaki, S.; Ohkubo, K.; Kojima, T.; Fukuzumi, S.
Dalton Trans. 2012, 41, 10006-10013. - Factors that Control Catalytic Two- vs Four-Electron Reduction of Dioxygen by Copper Complexes
Fukuzumi, S.; Tahsini, L.; Lee, Y.-M.; Ohkubo, K.; Nam, W.; Karlin, K. D.
J. Am. Chem. Soc. 2012, 134, 7025-7035. - Utilization of Photoinduced Charge-Separated State of Donor-Acceptor-Linked Molecules for Regulation of Cell Membrane Potential and Ion Transport
Numata, T.; Murakami, T.; Kawashima, F.; Morone, N.; Heuser, J. E.; Takano, Y.; Ohkubo, K.; Fukuzumi, S.; Mori, Y.; Imahori, H.
J. Am. Chem. Soc. 2012, 134, 6092-6095. - Synthesis and Photodynamics of Fluorescent Blue BODIPY-Porphyrin Tweezers Linked by Triazole Rings
Eggenspiller, A.; Takai, A.; El-Khouly, M. E.; Ohkubo, K.; Gros, C. P.; Bernhard, C.; Goze, C.; Denat, F.; Barbe, J.-M.; Fukuzumi, S.
J. Phys. Chem. A 2012, 116, 3889-3898. - Copper(I)-Dioxygen Reactivity in a Sterically Demanding Tripodal Tetradentate tren Ligand. Formation and Reactivity of a Mononuclear Copper(II) End-on Superoxo Complex
Kobayashi, Y.; Ohkubo, K.; Nomura, T.: Kubo, M.; Fujieda, N.; Sugimoto, H.; Fukuzumi, S.; Goto, K.; Ogura, T.; Itoh, S.
Eur. J. Inorg. Chem. 2012, 4574-4578. - Formation of a Long-Lived Electron-Transfer State in Mesoporous Silica-Alumina Composites Enhances Photocatalytic Oxidation Reactivity
Fukuzumi, S.; Doi, K.; Itoh, A.; Suenobu, T.; Ohkubo, K.; Yamada, Y.; Karlin, K. D.
Proc. Natl. Acad. Sci. USA. 2012, 109, 15572-15577.
Highlighted in Yomiuri Shimbun (Aug. 6, 2012) - Strong Supramolecular Binding of Li+@C60 with Sulfonated meso-Tetraphenylporphyrins and Long-lived Photoinduced Charge Separation
Ohkubo, K.; Kawashima, Y.; Fukuzumi, S.
Chem. Commun. 2012, 48, 4314-4316. - “ON-OFF” Switching of Europium Complex Luminescence Coupled with Ligand Redox Process
Yano, M.; Matsuhira, K.; Tatsumi, M.; Kashiwagi, Y.; Nakamoto, M.; Oyama, M.; Ohkubo, K.; Fukuzumi, S.; Misaki, H.; Tsukube, H.
Chem. Commun. 2012, 48, 4082-4084. - Regulation of Redox Potential of a Pterin Derivative Bound to a Ruthenium(II) Complex by Intermolecular Hydrogen Bonding with Nucleobases
Inui, Y.; Miyazaki, S. Ohkubo, K.; Fukuzumi, S.; Kojima, T.
Angew. Chem. Int. Ed. 2012, 51, 4623-4627. - Determination of the Structural Features of a Long-Lived Electron-Transfer State of 9-Mesityl-10-methylacridinium Ion
Hoshino, M.; Uekusa, H.; Tomita, A.; Koshihara, S.; Sato, T.; Nozawa, S.; Adachi, S.; Ohkubo, K.; Kotani, H.; Fukuzumi, S.
J. Am. Chem. Soc. 2012, 134, 4569-4572.
Highlighted in The Nikkan Kogyo Shimbun
Highlighted in Science News
Highlighted in Photon Factory Activity Report 2011 - Photoinduced Electron Transfer in Supramolecular Complexes of π-Extended Viologen with Porphyrin Monomer and Dimer
Fukuzumi, S.; Amasaki, I.; Ohkubo, K.; Gros, C. P.; Guilard, R.; Barbe, J.-M.
RSC Adv. 2012, 2, 3741-3747. - Photocatalytic Alkoxylation of Benzene with 3-Cyano-1-methylquinolinium Ion
Ohkubo, K.; Kobayashi, T.; Fukuzumi, S.
Opt. Exp. 2012, 20, A360-A365. - Photoinduced Energy and Electron Transfer in Phenylethynyl-Bridged Zinc Porphyrin-Oligothienylene Vinylene-C60 Ensembles
Urbani, M.; Ohkubo, K.; Islam, D. M. S.; Fukuzumi, S.; Langa, F.
Chem.-Eur. J. 2012, 18, 7473-7485. - Formation of a Long-lived Electron-Transfer State of a Naphthalene-Quinolinium Ion Dyad and the π-dimer Radical Cation
Kotani, H.; Ohkubo, K.; Fukuzumi, S.
Faraday Discuss. 2012, 155, 89-102. - Long-Lived Long-Distance Photochemically Induced Spin-Polarized Charge Separation in b,b’-Pyrrolic Fused Ferrocene-Porphyrin-Fullerene Systems
Lee, S.-H.; Larsen, A. G.; Ohkubo, K.; Cai, Z.-L.; Reimers, J. R.; Fukuzumi, S.; Crossley, M. J.
Chem. Sci. 2012, 3, 257-269. - Photocatalytic Hydrogen Evolution with Ni Nanoparticles by Using 2-Phenyl-4-(1-naphthyl)quinolinium Ion as a Photocatalyst
Yamada, Y.; Miyahigashi, T.; Kotani, H.; Ohkubo, K.; Fukuzumi, S.
Energy Environ. Sci. 2012, 5, 6111-6118.
Selected as a Hot Articles
2011
- Multiple Photosynthetic Reaction Centers Composed of Supramolecular Assemblies of a Zinc Porphyrin Dendrimer with Pyridylnaphthalenediimide
Fukuzumi, S.; Ohkubo, K.; Saito, K.; Kashiwagi, Y.; Khoury, T.; Crossley, M. J.
J. Porphyrins Phthalocyanines 2011, 15, 1292-1298. - Phosphorescent Sensor for Biological Mobile Zinc
You, Y.; Lee, S.; Kim, T.; Ohkubo, K.; Chae, W.-S.; Fukuzumi, S.; Jhon, G.-J.; Nam, W.; Lippard, S.
J. Am. Chem. Soc. 2011, 133, 18328-18342. - Photochemical Activation of Ruthenium(II)-Pyridylamine Complexes Having a Pyridine-N-Oxide Pendant toward Oxygenation of Organic Substrates
Kojima, T.; Nakayama, K.; Sakaguchi, M.; Ogura, T.; Ohkubo, K.; Fukuzumi, S.
J. Am. Chem. Soc. 2011, 133, 17901-17911. - Synthesis, Photophysical, Electrochemical, Tumor-Imaging and Phototherapeutic Properties of Purpurinimide-N-substituted Cyanine Dyes Joined with Variable Length of Linkers
Williams, M. P. A.; Ethirajan, M.; Ohkubo, K.; Chen, P.; Pera, P.; Morgan, J.; Shibata, M.; Fukuzumi, S.; Kadish, K. M.; Pandey, R. K.
Bioconjugate Chem. 2011, 22, 2283-2295. - Ion-Controlled On-Off Switch of Electron Transfer from Tetrathiafulvalene Calix[4]pyrroles to Li+@C60
Fukuzumi, S.; Ohkubo, K.; Kawashima, Y.; Kim, D. S.; Park, J. S.; Jana, A.; Lynch, V.; Kim, D.; Sessler, J. L.
J. Am. Chem. Soc. 2011, 133, 15938-15941. - Photocatalytic Hydrogen Evolution under Highly Basic Conditions by Using Ru Nanoparticles and 2-Phenyl-4-(1-naphtyl)quinolinium Ion
Yamada, Y.; Miyahigashi, T.; Kotani, H.; Ohkubo, K.; Fukuzumi, S.
J. Am. Chem. Soc. 2011, 133, 16136-16145. - Reversible Photoredox Switching of Porphyrin-Bridged Bis-2,6-di-t-Butyl Phenols
Ishihara, S.; Hill, J. P.; Shundo, A.; Richards, G. J.; Labuta, J.; Ohkubo, K.; Fukuzumi, S.; Sato, A.; Elsegood, M. R. J.; Teat, S. J.; Ariga, K.
J. Am. Chem. Soc. 2011, 133, 16119-16126. - Multiple Photosynthetic Reaction Centres Using Zinc Porphyrinic Oligopeptide-Fulleropyrrolidine Supramolecular Complex
Fukuzumi, S.; Saito, K.; Ohkubo, K.; Troiani, V.; Qui, H.; Gadde, S.; D’Souza, F.; Solladié N.
Phys. Chem. Chem. Phys. 2011, 13, 17019-17022. - Direct Oxygenation of Benzene to Phenol Using Quinolinium Ions as Homogeneous Photocatalysts
Ohkubo, K.; Kobayashi, T.; Fukuzumi, S.
Angew. Chem. Int. Ed. 2011, 50, 8652-8655.
Highlighted in Chem-Station - An Efficient Fluorescence Sensor for Superoxide with an Acridinium Ion-Linked Porphyrin Triad
Kotani, H.; Ohkubo, K.; Crossley, M. J.; Fukuzumi, S.
J. Am. Chem. Soc. 2011, 133, 11092-11095. - Supramolecular Zinc Phthalocyanine-Imidazoyl Perylenebisimide Dyad and Triad: Synthesis, Complexation and Photophysical Studies
Céspedes-Guirao, F. J.; Ohkubo, K.; Fukuzumi, S.; Fernández-Lázaro, F.; Sastre-Santos, Á.
Chem. Asian J. 2011, 6, 3110-3121. - Metal-free Oxygenation of Cyclohexane with Oxygen Catalyzed by 9-Mesityl-10-methylacridinium and Hydrogen Chloride under Visible Light Irradiation
Ohkubo, K.; Fujimoto, A.; Fukuzumi, S.
Chem. Commun. 2011, 47, 8515-8517. - Multiple Photosynthetic Reaction Centres Composed of Supramolecular Assemblies of Zinc Porphyrin Dendrimers with a Fullerene Acceptor
Fukuzumi, S.; Saito, K.; Ohkubo, K.; Khoury, T.; Kashiwagi, Y.; Absalom, M. A.; Gadde, S.; D’Souza, F.; Araki, Y.; Ito, O. Crossley, M. J.
Chem. Commun. 2011, 47, 7980-7982. - Disproportionation of Dipyrrolylquinoxaline Radical Anions via the Internal Protons of the Pyrrole Moieties
Fukuzumi, S.; Mase, K.; Ohkubo, K.; Fu, Z.; Karnas, E.; Sessler, J. L.; Kadish, K. M.
J. Am. Chem. Soc. 2011, 133, 7284-7287. - Synthesis and Photophysics of Silicon Phthalocyanine-Perylenebisimide Triads connected through Rigid and Flexible Bridges
Céspedes-Guirao, F. J.; Martín-Gomis, L.; Ohkubo, K.; Fernández-Lázaro, F.; Fukuzumi, S.; Sastre-Santos, Á.
Chem.-Eur. J. 2011, 17, 9153-9163.
Selected as a Hot Topics - Annulation of Tetrathiafulvalene to the Bay Region of Perylenediimide: Fast Electron-Transfer Processes in Polar and Nonpolar Solvents
El-Khouly, M. E.; Jaggi, M.; Scmid, B.; Blum, C.; Liu, S.-X; Decurtins, S.; Ohkubo, K.; Fukuzumi, S.
J. Phys. Chem. C 2011, 115, 8325-8334. - Remarkable Regioselective Position-10 Bromination of Bacteriopyropheophorbide-a and Ring-B Reduced Pyropheophorbide-a
Ethirajan, M.; Joshi, P.; William, W. H. III; ; Ohkubo, K.; Fukuzumi, S.; Pandey, R. K.
Org. Lett. 2011, 13, 1956-1959. - Formation of a Hybrid Compound Composed of a Saddle-Distorted Tin(IV)-Porphyrin and a Keggin-Type Heteropolyoxometalate to Undergo Intramolecular Photoinduced Electron Transfer
Yokoyama, A.; Kojima, T.; Ohkubo, K.; Shiro, M.; Fukuzumi, S.
J. Phys. Chem. A 2011, 115, 986-997. - Post-translational His-Cys Cross Linkage Formation in Tyrosinase Induced by Copper(II)-Peroxo Species
Fujieda, N.; Ikeda, T.; Murata, M.; Yanagisawa, S.; Aono, S.; Ohkubo, K.; Nagao, S.; Ogura, T.; Hirota, S.; Fukuzumi, S.; Nakamura, Y.; Hata, Y.; Itoh, S.
J. Am. Chem. Soc. 2011, 133,1180-1184. - Selective Photocatalytic Aerobic Bromination with Hydrogen Bromide via an Electron-Transfer State of 9-Mesityl-10-methylacridinium Ion
Ohkubo, K.; Mizushima, K.; Iwata, R.; Fukuzumi, S.
Chem. Sci. 2011, 2, 715-722.
Highlighted in Chem. Sci. Blog by Deputy Editor (Jan. 24, 2011) - Size‐ and Shape‐Dependent Activity of Metal Nanoparticles as Hydrogen‐ Evolution Catalysts:Mechanistic lnsights into the Photocatalytic Hydrogen Evolution
Kotani, H.; Hanazaki, R.; Ohkubo, K.; Yamada, Y.; Fukuzumi, S.
Chem.-Eur. J. 2011, 17, 2777-2785. - Photochemical Charge Separation Leading to Photocurrent Generation in Closely Positioned Donor-Boron Dipyrrin-Fullerene Triads
Wijesinghe, C. A.; El-Khouly, M. E.; Subbaiyan, N. K.; Supur, M. Zandler, M. E.; Ohkubo, K.; Fukuzumi, S.; D’Souza, F.
Chem.-Eur. J. 2011, 17, 3147-3156. - C60 Dimers Connected through Pleiadene Bridges: Fullerene Talking Each Other
Sastre-Santos, Á.; Parejo-Parados, C.; Martín-Gomis, L.; Ohkubo, K.; Fernández-Lázaro, F.; Fukuzumi, S.
J. Mater. Chem. 2011, 21, 1509-1515. - Stepwise vs. Concerted Pathways in Scandium Ion-Coupled Electron Transfer from Superoxide Ion to p-Benzoquinone Derivatives
Kawashima, T.; Ohkubo, K.; Fukuzumi, S.
Phys. Chem. Chem. Phys. 2011, 13, 3344-3352.
2010
- Crystal Structures and Solution Properties of Discrete Complexes Composed of Saddle-Distorted Molybdenum(V)-Dodecaphenylporphyrins and Keggin-Type Heteropolyoxometalates Linked by Direct Coordination
Yokoyama, A.; Kojima, T.; Ohkubo, K.; Fukuzumi
Inorg. Chem. 2010, 49, 11190-11198. - Stopped-Flow Kinetic Analysis of the Interaction of Cyclo[8]pyrrole with Anions
Karnas, E.; Johnson, K. A.; Kim, S. K.; Sessler, J. L.; Ohkubo, K.; Fukuzumi, S.
J. Am. Chem. Soc. 2010, 132, 16617-16622. - Ion-Mediated Electron Transfer in a Supramolecular Donor-Acceptor Ensemble
Park, J. S.; Karnas, E.; Ohkubo, K.; Chen, P. Kadish, K. M.; Fukuzumi, S.; Bielawski, C.; Hudnall, T. W.; Lynch, V. M.; Sessler, J. L.
Science 2010, 329, 1324-1327. - Synthesis and Photodynamics of 9-Mesitylacridinium Ion-Modified Gold Nanoclusters
Fukuzumi, S.; Hanazaki, R.; Kotani, H.; Ohkubo, K.
J. Am. Chem. Soc. 2010, 132, 11002-11003. - Formation of a Long-Lived Photoinduced Electron-Transfer State in an Electron Acceptor-Donor-Acceptor Porphyrin Triad Connected by Coordination Bonds
Honda, T.; Nakanishi, T.; Ohkubo, K.; Kojima, T.; Fukuzumi, S.
J. Phys. Chem. C 2010, 114, 14290-14299. - Supramolecular Structures and Photoelectronic Properties of the Inclusion Complex of a Cyclic Free-Base Porphyrin Dimer and C60
Nobukuni, H.; Shimazaki, Y.; Uno, H.; Naruta, Y.; Ohkubo, K.; Kojima, T.; Fukuzumi, S.; Seki, S.; Sakai, H.; Hasobe, T.; Tani, F.
Chem.-Eur. J. 2010, 16, 11611-11623. - The First Crystal Structure Determination of the Firefly Oxyluciferin and Detailed Study of Its Solution-state Spectroscopy: Implications for the Color Tuning Mechanism of Firefly Bioluminescence
Naumov, P.; Ozawa, Y.; Ohkubo, K.; Fukuzumi, S.
Luminescence 2010, 25, 81-82. - Structure and Photoinduced Electron Transfer Dynamics of a Series of Hydrogen-Bonded Supramolecular Complexes Composed of Electron Donors and a Saddle-Distorted Diprotonated Porphyrin
Honda, T.; Nakanishi, T.; Ohkubo, K.; Kojima, T.; Fukuzumi, S.
J. Am. Chem. Soc. 2010, 132, 10155-10163. - Synthesis, Crystal Structure and Photodynamics of π-Expanded Porphyrin-Fullerene Dyads Synthesized by Diels-Alder Reaction
Yamada, H.; Ohkubo, K.; Kuzuhara, D.; Takahashi, T.; Atula, S.; Okujima, T.; Ohara, K.; Ito, O.; Uno, H.; Ono, N.; Fukuzumi, S.
J. Phys. Chem. B 2010, 114, 14717-14728. - Photoinduced Electron Transfer in Photorobust Coumarins Linked with Electron Donors Affording Long Lifetimes of Triplet Charge-Separated States
Murakami, M.; Ohkubo, K.; Nanjo, T.; Souma, K.; Suzuki, N.; Fukuzumi, S.
ChemPhysChem 2010, 11, 2594-2605. - Multistep Electron Transfer Systems Based on Silicon Phthalocyanine, [60]Fullerene and Trinitrofluorenone
Martín-Gomis, L.; Ohkubo, K.; Fernández-Lázaro, F.; Fukuzumi, S.; Sastre-Santos, Á.
Chem. Commun. 2010, 46, 3944-3946. - Inter- and Intramolecular Photoinduced Electron Transfer of Flavin Derivatives with Extremely Small Reorganization Energies
Murakami, M.; Ohkubo, K.; Fukuzumi, S.
Chem.-Eur. J. 2010, 16, 7820-7832. - Synthesis and Photochemical Properties of α-Diketoporphyrins That Act as Excellent Precursors for the Corresponding Acenes
Yamada, H.; Kuzuhara, D.; Ohkubo, K.; Takahashi, T.; Okujima, T.; Uno, H.; Ono, N.; Fukuzumi, S.
J. Mater. Chem. 2010, 20, 3011-3024. - Photoinduced DNA Cleavage by Formation of ROS from Oxygen with a Neurotransmitter and Aromatic Amino Acids
Kawashima, T.; Ohkubo, K.; Fukuzumi, S.
Org. Biomol. Chem. 2010, 8, 994-996. - Construction of Sn(IV)-Porphyrin/Trinuclear Ruthenium Cluster Dyads Linked by Pyridine Carboxylates: Photoinduced Electron Transfer in the Marcus Inverted Region
Kojima, T.; Hanabusa, K.; Ohkubo, K.; Shiro, M.; Fukuzumi, S.
Chem.-Eur. J. 2010, 16, 3646-3655.
Selected as an Inside Cover Picture - Implementation of Redox Gradients in Hydrogen Bonded Complexes – Containing N,N-Dimethylaniline, Flavin and Fullerene
Murakami, M.; Ohkubo, K.; Hasobe, T.; Sgobba, V.; Guldi, D. M.; Wessendorf, F.; Hirsh, A.; Fukuzumi, S.
J. Mater. Chem. 2010, 20, 1457-1466. - Radical Scavenging Reactivity of Catecholamine Neurotransmitters and the Inhibition Effect for DNA Cleavage
Kawashima, T.; Ohkubo, K.; Fukuzumi, S.
J. Phys. Chem. B 2010, 114, 675-680. - Simultaneous Production of p-Tolualdehyde and Hydrogen Peroxide in Photocatalytic Oxygenation of p-Xylene and Reduction of Oxygen with 9-Mesityl-10-Methylacridinium Ion Derivatives
Ohkubo, K.; Mizushima, K.; Iwata, R.; Souma, K.; Suzuki, N.; Fukuzumi, S.
Chem. Commun. 2010, 46, 601-603. - Thienyl-substituted Methanofullerene Derivatives for Organic Photovoltaic Cells
Choi, J. H.; Son, K.-I; Kim, T.; Kim, K.; Ohkubo, K.; Fukuzumi, S.
J. Mater. Chem. 2010, 20, 475-482.
2009
- Photoinduced Change of Dielectric Permittivity in Molecular Doped Polymer Layer
Sakai, H.; Murata, H.; Murakami, M.; Ohkubo, K.; Fukuzumi, S.
Appl. Phys. Lett. 2009, 95, 252901-252903. - Mechanistic Insights into Hydride-Transfer and Electron-Transfer Reactions by a Manganese(IV)-Oxo Porphyrin Complex
Fukuzumi, S.; Fujioka, N.; Kotani, H.; Ohkubo, K.; Lee, Y.-M.; Nam, W.
J. Am. Chem. Soc. 2009, 131, 17127-17134. - Anion-Complexation-Induced Stabilization of Charge Separation
D’Souza, F.; Subbaiyan, N. K.; Xie, Y.; Hill, J. P.; Ariga, K.; Ohkubo, K.; Fukuzumi, S.
J. Am. Chem. Soc. 2009, 131, 16138-16146. - Structure and Photoelectrochemical Properties of a Self-Assembled Porphyrin Nanotube Including C60 Molecules
Nobukuni, H.; Tani, F.; Shimazaki, Y.; Naruta, Y.; Ohkubo, K.; Nakanishi, T.; Kojima, T.; Fukuzumi, S.; Seki, S.
J. Phys. Chem. C 2009, 113, 19694-19699. - Intramolecular Base-Accelerated Radical-Scavenging Reaction of a Planar Catechin Derivative Having a Lysine Moiety
Fukuhara, K.; Nakanishi, I.; Ohkubo, K.; Obara, Y.; Tada, A.; Imai, K.; Ohno, A.; Nakamura, A.; Ozawa, T.; Urano, S.; Saito, S.; Fukuzumi, S.; Anzai, K.; Miyata, N.; Okuda, H.
Chem. Commun. 2009, 6180-6182. - Metalloporphycenes: Synthesis and Characterization of (Pentamethylcyclopentadienyl)ruthenium Sitting-Atop and π-Complexes
Cuesta, L.; Karnas, E.; Lynch, V. M.; Chen, P.; Shen, J.; Kadish, K. M.; Ohkubo, K.; Fukuzumi, S.; Sessler, J. L.
J. Am. Chem. Soc. 2009, 131, 13538-13547. - Structure and Spectroscopy of Oxyluciferin, the Light Emitter of the Firefly Bioluminescence
Naumov, P.; Ozawa, Y.; Ohkubo, K.; Fukuzumi, S.
J. Am. Chem. Soc. 2009, 131, 11590-11605. - Synthesis and Photoinduced Electron Transfer of Phthalocyanine-Perylenebisimide Pentameric Arrays
Céspedes-Guirao, F. J.; Ohkubo, K.; Fukuzumi, S.; Sastre-Santos, Á.; Fernández-Lázaro, F.
J. Org. Chem. 2009, 74, 5871-5880. - Change in Site of Electron Transfer Reduction of a Zinc Quinoxalinoporphyrin-Gold Quinoxalinoporphyrin Dyad by Binding of Scandium Ion and the Resulting Remarkable Elongation of the Lifetime of the Charge-Shifted State
Ohkubo, K.; Garcia, R.; Sintic, P. J.; Khoury, T.; Crossley, M. J.; Kadish, K. M.; Fukuzumi, S.
Chem.-Eur. J. 2009, 15, 10493-10503. - Aliphatic C-H Bond Activation Initiated by a (μ-η2:η2-Peroxo)dicopper(II) Complex in Comparison with Cumylperoxyl Radical
Matsumoto, T.; Ohkubo, K.; Honda, K.; Yazawa, A.; Furutachi, H.; Fujinami, S.; Fukuzumi, S.; Suzuki, M.
J. Am. Chem. Soc. 2009, 131, 9258-9267. - Photosynthetic Reaction Center Mimicry: Low-Reorganization Energy Driven Charge Stabilization in Self-Assembled Cofacial Zinc Phthalocyanine Dimer-Fullerene Conjugate
D’Souza, F.; Maligaspe, E.; Ohkubo, K.; Zandler, M. E.; Subbaiyan, N. K.; Fukuzumi, S.
J. Am. Chem. Soc. 2009, 131, 8787-8797. - Tuning Charge Transfer Energetics in Reaction Center Mimics via Th-Functionalized Fullerenes
Spänig, F.; Kovacs, C.; Hauke, F.; Hartnagel, U.; Ohkubo, K.; Fukuzumi, S.; Guldi, D. M.; Hirsch, A.
J. Am. Chem. Soc. 2009, 131, 8180-8195. - In Vitro Heavy-Atom Effect of Palladium(II) and Platinum(II) Complexes of Pyrrolidine-Fused Chlorin in Photodynamic Therapy
Obata, M.; Hirohara, S.; Tanaka, R.; Kinoshita, I.; Ohkubo, K.; Fukuzumi, S.; Tanihara, M.; Yano, S.
J. Med. Chem. 2009, 52, 2747-2753. - Charge Separation in Metallomacrocycle Complexes Linked with Electron Acceptors by Axial Coordination
Fukuzumi, S.; Honda, T.; Ohkubo, K.; Kojima, T.
Dalton Trans. 2009, 3880-3889.
Selected as a Cover Picture - Catalytic Activity of Biscobalt Porphyrin-Corrole Dyads Towards the Reduction of Dioxygen
Kadish. K. M.; Frémond, L.; Shen, J.; Chen, P.; Ohkubo, K.; Fukuzumi, S.; Ojaimi, M. E.; Gros, C. P.; Barbe, J.-M.; Guilard, R.
Inorg. Chem. 2009, 48, 2571-2582. - Reorganization Energies of Diprotonated and Saddle-Distorted Porphyrins in Photoinduced Electron-Transfer Reduction Controlled by Conformational Distortion Nakanishi, T.; Kojima, T.; Ohkubo, K.; Fukuzumi, S. J. Am. Chem. Soc. 2009, 131, 577-584.
2008
- Photoconductivity of Porphyrin Nanochannels Composed of Diprotonated Porphyrin Dications with Saddle Distortion and Electron Donors
Nakanishi, T.; Kojima, T.; Ohkubo, K.; Hasobe, T.; Nakayama, K.; Fukuzumi, S.
Chem. Mater. 2008, 21, 7492-7500.
Selected as a Cover Picture - Metal Quinolinolate–Fullerene(s) Donor-Acceptor Complexes: Evidence for Organic LED Molecules Acting as Electron Donors in Photoinduced Electron-Transfer Reactions
D’Souza, F.; Maligaspe, E.; Zandler, M. E.; Subbaiyan, N. K.; Ohkubo, K.; Fukuzumi, S.
J. Am. Chem. Soc. 2008, 130, 16959-16967. - “Umpolung” Photoinduced Charge Separation in an Anion-bound Supramolecular Complex
Sessler, J. L.; Karnas, E.; Kim, S. K.; Ou, Z.; Zhang, M.; Kadish, K. M.; Ohkubo, K.; Fukuzumi, S.
J. Am. Chem. Soc. 2008, 130, 15256-15257. - Formation of Dodecaphenylporphodimethene via Facile Protonation of Saddle-Distorted Dodecaphenylporphyrin
Kojima, T.; Hanabusa, K.; Ohkubo, K.; Shiro, M.; Fukuzumi, S.
Chem. Commun. 2008, 6513-6515. - Proton Shift upon One-Electron Reduction in Ruthenium-Coordinated Pterins
Miyazaki, S.; Ohkubo, K.; Kojima, T.; Fukuzumi, S.
Angew. Chem., Int. Ed. 2008, 47, 9669-9672. - Adiabatic Photoinduced Electron Transfer and Back Electron Transfer in a Series of Axially-Substituted Silicon Phthalocyanine Triads
Matrín-Gomis, L.; Ohkubo, K.; Fernández-Lázaro, F.; Fukuzumi, S.; Sastre-Santos, Á.
J. Phys. Chem. C 2008, 112, 17694-17701. - (Pentamethylcyclopentadienyl)ruthenium π-Complexes of Metalloporphyrins: Platforms with Novel Photo- and Electrochemical Properties
Cuesta, L.; Karnas, E.; Kynch, V. M.; Sessler, J. L.; Kajonkijya, W.; Zhu, W.; Zhang, M.; Ou, Z.; Kadish, K. M.; Ohkubo, K.; Fukuzumi, S.
Chem.-Eur. J. 2008, 14, 10206-10210. - Control of Photoinduced Electron Transfer in Zinc Phthalocyanine-Perylenediimide Dyad and Triad by Magnesium Ion
Fukuzumi, S.; Ohkubo, K.; Oritz, J.; Gutiérrez, A. M.l Fernández-Lázaro, F.; Sastre-Santos, Á.
J. Phys. Chem. A 2008, 112, 10744-10752. - Corrole-Fullerene Dyads: Formation of Long-Lived Charge-Separated States in Non-Polar Solvents
D’Souza, F.; Chita, R.; Ohkubo, K.; Tasior, M.; Subbaiyan, N. K.; Zandler, M. E.; Rogacki, M.; Gryko, D. T.; Fukuzumi, S.
J. Am. Chem. Soc. 2008, 130, 14263-14272. - Highly Selective Synthesis of the Ring-B Reduced Chlorins by Ferric Chloride Mediated Oxidation of Bacteriochlorins: Effects of the Fused Imide vs Isocyclic Ring in Photophysical and Electrochemical Properties
Liu, C.; Dobhal, M. P.; Ethirajan, M.; Missert, J. R.; Pandey, R. K.; Balasubramanian, S.; Sukumaran, D. K.; Zhang, M.; Kadish, K. M.; Ohkubo, K.; Fukuzumi, S.
J. Am. Chem. Soc. 2008, 130, 14311-14323. - A Discrete Supramolecular Conglomerate Composed of Two Saddle-Distorted Zinc(II)-Phthalocyanine Complexes and a Doubly Protonated Porphyrin with Saddle-Distortion Undergoing Efficient Photoinduced Electron Transfer
Kojima, T.; Honda, T.; Ohkubo, K.; Shiro, M.; Kusukawa, T.; Fukuda, T.; Kobayashi, N.; Fukuzumi, S.
Angew. Chem., Int. Ed. 2008, 47, 6712-6716.
Selected as an Inside Cover Picture - Why had Long-lived Electron-transfer States of Donor-substituted 10-Methylacridinium Ions been Overlooked? Formation of the Dimer Radical Cations Detected in the Near-IR Region
Fukuzumi, S.; Kotani, H.; Ohkubo, K.
Phys. Chem. Chem. Phys. 2008, 10, 5159-5162. - Exciplex Mediated Photoinduced Electron Transfer Reactions of Phthalocyanine-Fullerene Dyads
Niemi, M.; Tkachenko, N. V.; Efimof, A.; Lehtivuori, H.; Ohkubo, K.; Fukuzumi, S.; Lemmetyinen, H.
J. Phys. Chem. A 2008, 112, 6884-6892. - Androgynous Porphyrins. Silver(II) Quinoxalinoporphyrins Act as Both Good Electron Donors and Acceptors
Fukuzumi, S.; Ohkubo, K.; Zhu, W.; Sintic, M.; Khoury, T.; Sintic, P. J.; E, W.; Ou, Z.; Crossley, M. J.; Kadish, K. M.
J. Am. Chem. Soc. 2008, 130, 9451-9458. - Clarification of the Oxidation State of Cobalt Corroles in Heterogeneous and Homogeneous Catalytic Reduction of Dioxygen
Kadish, K. M.; Shen, J.; Frémond, L.; Chen, P.; Ojaimi, M. E.; Chkiynda, M.; Gros, C. P.; Barbe, J.-M.; Ohkubo, K.; Fukuzumi, S.; Guilard, R.
Inorg. Chem. 2008, 47, 6726-6737. - Intermolecular vs Intramolecular Photoinduced Electron Transfer from Nucleotides in DNA to Acridinium Ion Derivatives in Relation with DNA Cleavage
Tanaka, M.; Yukimoto, K.; Ohkubo, K.; Fukuzumi, S.
J. Photochem. Photobiol. A 2008, 197 206-212. - DNA Cleavage Induced by Photoirradiation of Coenzyme B12 and Organocobaloximes without Dioxygen
Tanaka, M.; Ohkubo, K.; Fukuzumi, S.
J. Photochem. Photobiol. A 2008, 197, 94-100. - Metal Bacteriochlorins Which Act as Dual Singlet Oxygen and Superoxide Generators
Fukuzumi, S.; Ohkubo, K.; Zheng, X.; Chen, Y.; Pandey, R. K.; Zhan, R.; Kadish, K. M.
J. Phys. Chem. B 2008, 112, 2738-2746. - Face-to-Face Held Pacman Type Porphyrin-Fullerene Dyads: Design, Synthesis, Charge Transfer Interactions and Photophysical Studies
D’Souza, F.; Maligaspe, E.; Karr, P. A.; Schumacher, A. L.; Ojaimi, M. E.; Gros, C. P.; Barbe, J.-M.; Ohkubo, K.; Fukuzumi, S.
Chem.-Eur. J. 2008, 14, 674-681. - Contrasting Photodynamics between Dithiapyrene-C60 and Pyrene-C60 Dyads
Guldi, D. M.; Spänig, F.; Kreher, D.; Perepichka, I. F.; Bryce, M. R.; Ohkubo, K.; Fukuzumi, S.
Chem.-Eur. J. 2008, 14, 250-258. - Formation of Hydrogen Peroxide from Coal Tar as Hydrogen Sources using 9-Mesityl-10-methylacridinium Ion as an Effective Photocatalyst
Kotani, H.; Ohkubo, K.; Fukuzumi, S.
Appl. Catal. B Environ. 2008, 77, 317-324. - Enhanced Radical-scavenging Activity of Naturally-oriented Artepillin C Derivatives
Manda, S.; Nakanishi, I.; Ohkubo, K.; Uto, Y.; Kawashima, T.; Hori, H.; Fukuhara, K.; Okuda, H.; Ozawa, T.; Ikota, N.; Fukuzumi, S.; Anzai, K.
Chem. Commun. 2008, 626-628. - Synthesis and Characterization of Novel Ferrocene-Containing Pyridylamine Ligands and Their Ruthenium(II) Complexes: Electronic Communication through Hydrogen-bonded Amide Linkage
Kojima, T.; Noguchi, D.; Nakayama, T.; Inagaki, Y.; Shirota, Y.; Yoshizawa, K.; Ohkubo, K.; Fukuzumi, S.
Inorg. Chem. 2008, 112, 635-642. - Electron-Transfer and Acid-Base Properties of a Two-Electron Oxidized Form of Quaterpyrrole that Acts as Both an Electron Donor and an Acceptor
Zhang, M.; E, W.; Ohkubo, K.; Sanchez-Garcia, D.; Yoon, D.-W.; Sessler, J. L.; Fukuzumi, S.; Kadish, K. M.
J. Phys. Chem. A 2008, 47, 1633-1642. - Control of the Orbital Delocalization and Implications for Molecular Rectification in the Radical Anions of Porphyrins with Coplanar 90。 and 180。 b,b’-Fused Extens
E, W.; Kadish, K. M.; Sintic, P. J.; Khoury, T.; Govenlock, L. J.; Ou, Z.; Shao, J.; Ohkubo, K.; Reimers, J. R.; Fukuzumi,
S.; Crossley, M. J. J. Phys. Chem. A 2008, 112, 556-570. - Does Bimolecular Charge Recombination in Highly Exergonic Electron Transfer Afford the Triplet Excited State or the Ground State of a Photosensitizer?
Murakami, M.; Ohkubo, K.; Mandal, P.; Ganguly, T.; Fukuzumi, S.
J. Phys. Chem. A 2008, 112, 635-642. - Proton-Coupled Electron Transfer in Ruthenium(II)-Pterin Complexes: Formation of Ruthenium-Coordinated Pterin Radicals and Their Electronic Structures
Miyazaki, S.; Kojima, T.; Sakamoto, T.; Matsumoto, T.; Ohkubo, K.; Fukuzumi, S.
Inorg. Chem. 2008, 47, 333-343. - Spectroscopic Characterization of Photolytically Generated Radical Ion Pairs in Single-Wall Carbon Nanotubes Bearing Surface-Immobilized Tetrathiafulvalens
Herranz, M. A.; Ehli, C.; Campidelli, S.; Gutierrez, M.; Hug, G. L.; Ohkubo, K.; Fukuzumi, S.; Prato, M.; Matin, N.; Guldi, D. M.
J. Am. Chem. Soc. 2008, 130, 66-73.
2007
- Nitroxyl Radicals: Electrochemical Redox Behaviour and Structure Activity Relationships
Manda, S.; Nakanishi, I.; Ohkubo, K.; Yakumaru, H.; Matsumoto, K.; Ozawa, T.; Ikota, N.; Fukuzumi, S.; Anzai, K.
Org. Biomol. Chem. 2007, 5, 3951-3955.
Selected as an Inside Cover Picture - Involvement of Electron Transfer in the Radical-scavenging Reaction of Resveratol
Nakanishi, I.; Shimada, T.; Ohkubo, K.; Manda, S.; Shimizu, T.; Urano, S.; Okuda, H.; Miyata, N. Ozawa, T.; Anzai, K.; Fukuzumi, S.; Ikota, N.; Fukuhara, K.
Chem. Lett. 2007, 36, 1276-1277. - Design and Synthesis of Polymetallic Complexes Based on meso-Calix[4]pyrrole: Platform for Multielectron Chemistry
Custa, L.; Gross, D.; Lynch, V. M.; Ou, Z.; Kajokiiya, W.; Ohkubo, K.; Fukuzumi, S.; Kadish, K. M.; Sessler, J. L.
J. Am. Chem. Soc. 2007, 129, 11696-11697. - Photophysical and Electrochemical Characteristics and Cross-Linking of STAT-3 Proteins by an Efficient Bifunctional Agent for Fluorescence Image-guided Photodynamic Therapy
Chen, Y.; Ohkubo, K.; Zhang, M.; E, W.; Liu, W.; Pandey, S. K.; Ciesielski, M.; Baumann, H.; Fukuzumi, S.; Kadish, K. M.; Fenstermaker, R.; Oseroff, A.; Pandey, R. K.
Photochem. Photobiol. Sci. 2007, 6, 1257-1267. - Synthesis and Photophysical Studies of a New Non aggregated C60-Silicon Phthalocyanine-C60 Triad
Martin-Gomis, L.; Ohkubo, K.; Fernandez-Lazaro, F.; Sastre-Santos, A.; Fukuzumi, S.
Org. Lett. 2007, 9, 3441-3444. - Enhanced Photoinduced Oligomerization of Fullerene via Radical Coupling between Fullerene Radical Cation and Radical Anion using 9-Mesityl-10-methylacridinium Ion
Ohkubo, K.; Iwata, R.; Yanagimoto, T.; Fukuzumi, S.
Chem. Commun. 2007, 3139-3142. - Selective Inclusion of Electron-Donating Molecules into Porphyrin Nanochannels Derived from Self-Assembly of Saddle-Distorted Dicationic Porphyrins and Photoinduced Electron Transfer from the Guest Molecules to the Porphyrin Dications
Kojima, T.; Nakanishi, T.; Harada, R.; Ohkubo, K.; Yamauchi, S.; Fukuzumi, S.
Chem.-Eur. J. 2007, 36, 8714-8725. - A Tightly Coupled Bis(zinc(II)phthalocyanine)-Perylenediimide Ensemble to Yield Long-Lived Radical Ion Pair State
Jimenez, A.; Spanig, F.; Rodriguez-Morgade, M. S.; Ohkubo, K.; Fukuzumi, S.; Guldi, D. M.; Torres, T.
Org. Lett. 2007, 9, 2481-2484. - A Discrete Assembly of a Distorted Mo(IV)-Porphyrin with a Directly Coordinated Keggin-Type Polyoxometalate
Yokoyama, A.; Kojima, T.; Ohkubo, K.; Fukuzumi, S.
Chem. Commun. 2007, 3997-3999.
Selected as a Cover Picture, Highlighted in Chemical Science - Quinoxalino[2,3-b‘]porphyrins Behave as p-Expanded Porphyrin upon One-Electron Reduction: Broad Control of the Degree of Delocalization through Substitution at the Macrocycle Periphery
Kadish, K. M.; E, W.; Sintic, P. J.; Ou, Z.; Jianguo, S.; Ohkubo, K.; Fukuzumi, S.; Govenlock, L. J.; McDonald, J. A.; Try, A.; Cai, Z.-L.; Reimers. J. R.; Crossley, M. J.
J. Phys. Chem. B 2007, 111, 8762-8774. - Effect of Solvent Polarity on the One-Electron Oxidation of Cyclic Nitroxyl Radicals
Manda, S.; Nakanishi, I.; Ohkubo, K.; Kawashima, T.; Matsumoto, K.; Ozawa, T.; Fukuzumi, S.; Ikota, N.; Anzai, K.
Chem. Lett. 2007, 36, 914-915. - Redox Behavior of Cyclo[6]pyrrole in the Formation of a Uranyl Complex
Melfi, P. J.; Kim, S. K.; Lee, J. T.; Bolze, F.; Seidel, D.; Lynch, V. M.; Veauthier, J. M.; Gaunt, A. J.; Neu, M. P.; Ou. Z.; Kadish, K. M.; Fukuzumi, S.; Ohkubo, K.; Sessler, J. S.
Inorg. Chem. 2007, 46, 5143-5145. - Synthesis and Characterization of Mononuclear Ruthenium(III)-Pyridylamine Complexes and Mechanistic Insights into Their Catalytic Alkene Functionalization with m-Chloroperbenzoic Acid
Kojima, T.; Hayashi, K.; Iizuka, S.; Tani, F.; Naruta, Y.; Kawano, M.; Ohashi, Y.; Hirai, Y.; Ohkubo, K.; Fukuzumi, S.
Chem.-Eur. J. 2007, 13, 8212-8222. - A Long-Lived o-Semiquinone Radical Anion Is Formed from N-b-Alanyl-5-S-glutathionyl-3,4-dihydroxyphenylalanine (5-S-GAD), An Insect-Derived Antibacterial Substance
Akiyama, N.; Nakanishi, I.; Ohkubo, K.; Satoh, N.; Tachiya, K.; Nishikawa, T.; Fukuzumi, S.; Ikota, N.; Ozawa, T.; Tsujimoto, M.; Natori, S.
J. Biochem. 2007, 142, 41-48. - Photoinduced Electron Transfer in a b,b’-Pyrrolic Fused Ferrocene-Porphyrin-Fullerene
Curiel, D.; Ohkubo, K.; Reimers, J. R.; Fukuzumi, S.; Crossley, M. J.
Phys. Chem. Chem. Phys. 2007, 9, 5260-5266. - Intramolecular Electron Transfer within the Substituted Tetrathiafulvalene-Quinone Dyads: Facilitated by Metal Ion and Photomodulation in the Presence of Spiropyran
Wu, H.; Zhang, D.; Su, L.; Ohkubo, K.; Zhang, C.; Yin, S.; Mao, L.; Shuai, Z.; Fukuzumi, S.; Zhu, D.
J. Am. Chem. Soc. 2007, 129, 6839-6846. - Porphyrin-Diones and Porphyrin-Tetraones: Reversible Redox Units being Localized within the Porphyrin Macrocycle and Their Effect on Tautomerism
Kadish, K. M.; E,W.; Zhan,R.; Khoury, T.; Govenlock, L. J.; Prashar,J. K. . Sintic, P. J.; Ohkubo, K.; Fukuzumi, S.; Crossley, M. J.
J. Am. Chem. Soc. 2007, 129, 6576-6588. - Electron-Transfer Oxidation Properties of Substituted Bi-, Ter-, and Quaterpyrroles
W. E, Ohkubo, K.; Sanchez-Garcia, D.; Zhang, M.; Sessler, J. L.; Fukuzumi, S.; Kadish, K. M.
J. Phys. Chem. B 2007, 111, 4320-4326. - Model Studies of 6,7-Indolequinone Cofactors of Quinohemoprotein Amine Dehydrogenases
Murakami, Y.; Yoshimoto, N.; Fujieda, N.; Ohkubo, K.; Kano, K.; Fukuzumi, S.; Itoh, S.
J. Org. Chem. 2007, 72, 3369-3380. - Scandium Ion-Accelerated Scavenging Reaction of Cumylperoxyl Radical by a Cyclic Nitroxyl Radical via Electron Transfer
Nakanishi, I.; Kawaguchi, K.; Ohkubo, K.; Kawashima, T.; Manda, S.; Kanazawa, H.; Takeshita, K.; Anzai, K.; Ozawa, T.; Fukuzumi, S.; Ikota, N.
Chem. Lett. 2007, 36, 378-379. - Modulation of Characteristics of a Ruthenium-Coordinated Flavin Analog Showing an Unprecedented Coordination Mode Miyazaki, S.; Ohkubo, K.; Kojima, T.; Fukuzumi, S.
Angew. Chem. Int. Ed. 2007, 46, 905-908.
Selected as a VIP paper - Fullerene Acting as an Electron Donor in a Donor-Acceptor Dyad to Attain the Long-Lived Charge-Separated State by Complexation with Scandium Ion
Ohkubo, K.; Ortiz, J.; Martin-Gomis, L.; Fernandez-Lazazro, F.; Sastre-Santos, A; Fukuzumi, S.
Chem. Commun. 2007, 589-591. - Efficient Photocatalytic Hydrogen Evolution without an Electron Mediator Using a Simple Electron Donor-Acceptor Dyad
Kotani, H.; Ono, T.; Ohkubo, Fukuzumi, S.
Phys. Chem. Chem. Phys. 2007,9, 1487-1492.
Selected as a Highlight in Chemical Science - Formation of a Charge-Separated State of a Fullerene-Trinitrofluorenone Dyad by Complexation with Scandium Ion
Ohkubo, K.; Ortiz, J.; Martin-Gomis, L.; Fernndez-Lzaro, F.; Sastre-Santos, .; Fukuzumi, S.
ECS Trans. 2007, 2, 15-25. - p-Complex Formation between a Bisporphyrin and Acridinium Ion and the Photodynamics
Tanaka, M.; Ohkubo, K.; Gros, C.; Guilard, R.; Fukuzumi, S.
ECS Trans. 2007, 12, 167-176.
2006
- Photocatalytic Formation of Dimethyllepidopterene from 9,10-Dimethylanthracene via Electron-Transfer Oxidation
Ohkubo, K.; Iwata, R.; Miyazaki, S.; Kojima, T.; Fukuzumi, S.
Org. Lett. 2006, 8, 6079-6082. - Spin-Site Exchange System Constructed from Endohedral Metallofullerenes and Organic Donors
Tsuchiya, T.; Sato, K.; Kurihara, H.; Wakahara, T; Maeda, Y.; Akasaka, T.; Ohkubo, K.; Fukuzumi, S.; Kato, T.; Nagase, S.
J. Am. Chem. Soc. 2006, 128, 14418-14419. - An Extremely Long-Lived Charge-Separated State of Zinc Tetraphenylporphyrin Coordinated with Pyridylnaphthalenediimide
Saito, K.; Kashiwagi, Y.; Ohkubo, K.; Fukuzumi, S.
J. Porphyrins Phthalocyanines 2006, 10, 1371-1379. - Viologen-Modified Platinum Clusters Acting as an Efficient Catalyst in Photocatalytic Hydrogen Evolution
Kotani, H.; Ohkubo, K.; Takai, Y.; Fukuzumi, S.
J. Phys. Chem. B 2006, 110,24047-24053. - Activation of Electron-Transfer Reduction of Oxygen by Hydrogen Bond Formation of Superoxide Anion with Ammonium Ion
Ohkubo, K.; Kitaguchi, H.; Fukuzumi, S.
J. Phys. Chem. A 2006, 110, 11613-11616. - Reductive DNA Cleavage Induced by UVA Photoirradiation of NADH without Oxygen
Tanaka, M.; Ohkubo, K.; Fukuzumi, S.
J. Am. Chem. Soc. 2006, 128,12372-12373. - Persistent Electron-Transfer State of a π-Complex of Acridinium Ion Inserted between Porphyrin Rings of Cofacial Bisporphyrins
Tanaka, M.; Ohkubo, K.; Gross, C. P.; Guilard, R.; Fukuzumi, S.
J. Am. Chem. Soc. 2006, 128, 14625-14633. - DNA Cleavage by UVA Irradiation of NADH with Dioxygen via Radical Chain Processes
Tanaka, M.; Ohkubo, K.; Fukuzumi, S.
J. Phys. Chem. A 2006, 110, 11214-11218. - Photocatalytic Electron-Transfer Oxidation of Triphenylphosphine and Benzylamine with Molecular Oxygen via Formation of Radical Cations and Superoxide Ion
Ohkubo, K.; Nanjo, T.; Fukuzumi, S.
Bull. Chem. Soc. Jpn. 2006, 79, 1489-1500.
Selected as a BCSJ Award Article and a Cover Picture - Host-Guest Complexation of Endohedral Metallofullerene with Azacrown Ether and Its Application
Tsuchiya, T.; Sato, K.; Kurihara, H.; Wakahara, T; Nakahodo, T.; Maeda, Y.; Akasaka, T.; Ohkubo, K.; Fukuzumi, S.; Kato, T.; Mizorogi, N.; Kobayashi, K.; Nagase, S.
J. Am. Chem. Soc. 2006, 128, 6699-6703. - Photoinduced Electron-Transfer Dynamics and Long-lived CS States of Donor-Acceptor Linked Dyads and a Triad Containing a Gold Porphyrin in Nonpolar Solvents
Ohkubo, K.; Sintic, P. J.; Tkachenko, N. V.; E, W.; Ou, Z.; Shao, J.; Kadish, K. M.; Crossley, M. J.; Fukuzumi, S.
Chem. Phys. 2006, 326, 3-14. - Direct Detection of Nucleotide Radical Cations Produced by Electron-Transfer Oxidation of DNA Bases with Electron-Transfer State of 9-Mesityl-10-methylacridinium Ion and Resulting Efficient DNA Cleavage without Oxygen
Ohkubo, K.; Yukimoto, K.; Fukuzumi, S.
Chem. Commun. 2006, 2504-2506. - Solvent-Free Selective Photocatalytic Oxidation of Benzyl Alcohol to Benzaldehyde by Molecular Oxygen using 9-Phenyl-10-methylacridinium
Ohkubo, K.; Suga, K.; Fukuzumi, S.
Chem. Commun. 2006, 2018-2020. - Organotin Perfluorooctanesulfonates as Air-Stable Lewis Acid Catalysts: Synthesis, Characterization, and Catalysis
An, D. L.; Peng, Z.; Orita, A.; Kurita, A.; Man-e, S.; Ohkubo, K.; Li, X.; Fukuzumi, S.; Otera, J.
Chem. Eur. J. 2006, 12, 1642-1647.
Selected as a VIP paper - Structual Basis for DNA-Cleaving Activity of Resveratrol in the Presence of Cu(II)
Fukuhara, K.; Nagakawa, M.; Nakanishi, I.; Ohkubo, K.; Imai, K.; Urano, S.; Fukuzumi, S.; Ozawa, T.; Ikota, N.; Mochizuki, M.; Miyata, N.; Okuda, H.
Bioorg. Med. Chem. 2006, 14, 1437-1443. - Additivity Rule Holds in Hydrogen-Transfer Reactivity of Unsaturated Fatty Acids with a Peroxyl Radical: Mechanistic Insight into Lipoxygenase
Kitaguchi, H.; Ohkubo, K.; Ogo, S.; Fukuzumi, S.
Chem. Commun. 2006, 979-981. - Photocatalytic Oxygenation of Pivalic Acid with Molecular Oxygen via Photoinduced Electron Transfer Using 10-Methylacridinium Ions
Suga, K.; Ohkubo, K.; Fukuzumi, S.
J. Phys. Chem. A 2006, 110, 3860-3867. - Photocatalytic Oxygenation of Olefins with Oxygen. Isolation of 1,2-Dioxetane and the Photocatalytic O-O Bond Cleavage
Ohkubo, K.; Nanjo, T.; Fukuzumi, S.
Catal. Today 2006, 117, 356-361. - Hydrogen Abstraction from Neurotransmitters by Active Oxygen Species Facilitated by Intramolecular Hydrogen Bonding in the Radical Intermediates
Ohkubo, K.; Moro-oka, Y.; Fukuzumi, S.
Org. Biomol. Chem. 2006, 4, 999-1001. - Electron-Transfer Oxidation Properties of Unsaturated Fatty Acids and Mechanistic Insight into Lipoxygenases
Kitaguchi, H.; Ohkubo, K.; Ogo, S.; Fukuzumi, S.
J. Phys. Chem. A 2006, 110, 1718-1725.
2005
- Anti-chagasic Activity of Komaroviquinone is due to Generation of Reactive Oxygen Species Catalyzed by Trypanosoma cruzi Old Yellow Enzyme
Uchiyama, N.; Kabututu, Z.; Kubata, B. K.; Kiuchi, F.; Ito, M.; Tshubouchi, A.; Nakajima-Shimada, J.; Aoki, T.; Ohkubo, K.; Fukuzumi, S.; Martin, S. K.; Honma, G.; Urade, Y.
Antimicrob. Agents Chemother. 2005, 49, 5123-5126. - Selective Oxygenation of 4,4′-Dimethylbiphenyl with Molecular Oxygen, Catalyzed by 9-Phenyl-10-Methylacridinium Ion Via Photoinduced Electron Transfer
Suga, K.; Ohkubo, K.; Fukuzumi, S.
J. Phys. Chem. A 2005, 109, 10168-10175. - Efficient Photocatalytic Oxygenation of Aromatic Alkene to 1,2-Dioxetane with Oxygen via Electron Transfer
Ohkubo, K.; Nanjo, T.; Fukuzumi, S.
Org. Lett. 2005, 7, 4265-4268. - Hydroxyl Radical Generation via Photoreduction of a Simple Pyridine N-oxide by an NADH Analogue
Nakanishi, I.; Nishizawa, C.; Ohkubo, K.; Takeshita, K.; Suzuki, K. T.; Ozawa, T.; Hecht, S. M.; Tanno, M.; Sueyoshi, S.; Miyata, N.; Okuda, H.; Fukuzumi, S.; Ikota, N.; Fukuhara, K.
Org. Biomol. Chem. 2005, 3, 3263-3265. - Intramolecular Hydrogen Bonding in Bisphenol Developing Agents for Photothermographic Application
Akahori, H.; Morita, K.; Nishijima, A.; Mitsuhashi, T.; Ohkubo, K.; Fukuzumi, S.
J. Imag. Sci. Tech. 2005, 49, 381-388. - Charge Separation in a Nonfluorescent Donor-Acceptor Dyad Derived from Boron Dipyrromethene Dye, Leading to Photocurent Generation
Hattori, S.; Ohkubo, K.; Urano, Y.; Sunahara, H.; Nagano, T.; Wada, Y.; Tkacgenko, N. V.; Lemmetyinen, H.; Fukuzumi, S.
J. Phys. Chem. B 2005, 109, 15368-15375. - Misleading Effects of Impurities Derived from Extremely Long-Lived Electron-Transfer State of 9-Mesityl-10-methylacridinium Ion
Ohkubo, K.; Kotani, H.; Fukuzumi, S.
Chem. Commun. 2005, 4520-4522. - Formation of a Long-Lived Charge-Separated State of a Zinc Phthalocyanine-Perylenediimide Dyad by Complexation with Magnesium Ion
Fukuzumi, S.; Ohkubo, K.; Ortiz, J.; Gutierrez, A. M.; Fernandez-Lazaro, F.; Sastre-Santos, A.
Chem. Commun. 2005, 3814-3815. - Electrochemistry of [(TMpyP)MII]4+(X-)4(X- = Cl- or BPh4- ) and [(TMpyP)MIIICl]4+(Cl-)4 in N,N-Dimethylformamide Where M Is One of 15 Different Metal Ions
Van Caemelbecke, E.; Derbin, A.; Hambright, P.; Garcia, R.; Doukkali, A.; Saoiabi, A.; Ohkubo, K.; Fukuzumi, S.; Kadish, K. M.
Inorg. Chem. 2005, 44, 3789-3798. - Effects of DNA on Driving Force Dependence of Photoinduced Electron Transfer from the Excited State of Tris(2,2-bipyridine)ruthenium(II) to Intercalators in DNA. Distinction between Intra- and Inter-DNA Pathways
Fukuzumi, S.; Tanaka, M.; Nishimine, M.; Ohkubo, K.
J. Photochem. Photobiol. A Chem. 2005, 175, 79-88. - Direct ESR Detection of Pentadienyl Radicals and Peroxyl Radicals in Lipid Peroxidation: Mechanistic Insight into Regioselective Oxygenation in Lipoxygenases
Kitaguchi, H.; Ohkubo, K.; Ogo, S.; Fukuzumi, S.
J. Am. Chem. Soc. 2005, 127, 6605-6609. - Electron-Transfer Oxidation Properties of DNA Bases and DNA Oligomers
Fukuzumi, S.; Miyao, H.; Ohkubo, K.; Suenobu, T.
J. Phys. Chem. A 2005, 109, 3285-3294. - Electron-Transfer Mechanism in Radical-Scavenging Reactions by a Vitamin E Model in a Protic Medium
Nakanishi, I.; Kawashima, T.; Ohkubo, K.; Kanazawa, H.; Inami, K.; Mochizuki, M.; Fukuhara, K.; Okuda, H.; Itoh, S.; Fukuzumi, S.; Ikota, N.
Org. Biomol. Chem. 2005,3, 626-629. - Electron-Transfer Oxidation of Coenzyme B12 Model Compounds and Facile Cleavage of the Cobalt(IV)-Carbon Bond via Charge-Transfer Complexes with Bases. A Negative Temperature Dependence of the Rates
Ohkubo, K.; Fukuzumi, S.
J. Phys. Chem. A 2005, 109, 1105-1113.
2004
- Photocatalytic Oxygenation of Anthracenes and Olefins with Dioxygen via Selective Radical Coupling Using 9-Mesityl-10-methylacridinium Ion as an Effective Electron-Transfer Photocatalyst
Kotani, H.; Ohkubo, K.; Fukuzumi, S.
J. Am. Chem. Soc. 2004, 126, 15999-16006. - Spectral and Electrochemical Characterization of Highly Substituted Copper Corroles
Ou, Z.; Shao, J.; Zhao, H.; Ohkubo, K.; Wasbotten, I. H.; Fukuzumi, S.; Ghosh, A.; Kadish, K. M.
J. Porphyrins Phthalocyanines 2004, 8, 191-2004. - Effects of Ammonium Cations on Redox Potentials of Quinones and the Photoinduced Electron-Transfer Reactions
Okamoto, K.; Ohkubo, K.; Kadish, K. M.; Fukuzumi, S.
J. Phys. Chem. A 2004, 108, 10405-10413. - Rational Principles for Modulating Fluorescence Properties of Fluorescein
Ueno, T.; Urano, Y.; Setsukinai, K.; Takakusa, H.; Kojima, H.; Kikuchi, K.; Ohkubo, K.; Fukuzumi, S.; Nagano, T.
J. Am. Chem. Soc. 2004, 126, 14079-14085. - DNA Cleavage Induced by Thermal Electron Transfer from a Dimeric NADH Analog to Acridinium Ions in the Presence of Oxygen
Fukuzumi, S.; Yukimoto, K.; Ohkubo, K.
J. Am. Chem. Soc. 2004, 126, 12794-12795. - Drastic Changes in the Lifetime and Electron Transfer and Energy Transfer Reactivity of the Triplet Excited State of p-Benzoquinone by Complex Formation with Scandium Ion Salts
Fukuzumi, S.; Yuasa, J.; Ohkubo, K.; Guldi, D. M.
J. Phys. Chem. A 2004, 108, 10405-10413. - Photoelectrochemical Properties of Supramolecular Composite of Fullerene Nanoclusters and 9-Mesityl-10-carboxymethylacridinium Ion on SnO2
Hasobe, T.; Hattori, S.; Kotani, H.; Ohkubo, K.; Hosomizu, K.; Imahori, H.; Kamat, P. V.; Fukuzumi, S.
Org. Lett. 2004, 6, 3103-3106. - Enhancement Energy and Quantum Efficiencies of a Nanocrystalline Photoelectrochemical Cell Sensitized with a Donor-Acceptor Dyad Derived from Fluorescein
Hattori, S.; Hasobe, T.; Ohkubo, K.; Urano, T.; Nagano, T.; Wada, Y.; Yanagida, S.; Fukuzumi, S.
J. Phys. Chem. B 2004, 108, 152004-15205. - EPR Study on Stable Magnesium Complexes of the Phenoxyl Radicals Derived from a Vitamin E Model and Its Deuterated Derivatives
Nakanishi, I.; Matsumoto, S.; Ohkubo, K.; Fukuhara, K.; Okura, H.; Inami, K.; Mochizuki, M.; Ozawa, T.; Itoh, S.; Fukuzumi, S.; Ikota, N.
Bull. Chem. Soc. Jpn. 2004, 77, 1741-1744. - p-Complex Formation in Electron-Transfer Reactions of Porphyrins
Fukuzumi, S.; Hasobe, T.; Ohkubo, K. Crossley, M. J.; Kamat, P. V.; Imahori, H.
J. Porphyrins Phthalocyanines 2004, 8, 191-2004. - Substituent Effects on the Site of Electron Transfer During the First Reduction for Gold(III) Porphyrins
Ou, Z.; Kadish, K. M.; E, W.; Shao, J.; Sintic, P. J.; Ohkubo, K.; Fukuzumi, S.; Crossley, M. J.
Inorg. Chem. 2004, 43, 2078-2086. - Electron-Transfer State of 9-Mesityl-10-methylacridinium Ion with a Much Longer Lifetime and Higher Energy than that of Natural Photosynthetic Reaction Center
Fukuzumi, S.; Kotani, H.; Ohkubo, K.; Ogo, S.; Tkachenko, N. V.; Lemmetyinen, H.
J. Am. Chem. Soc. 2004, 126, 1600-1601. - A Planar Catechin Analogue Having a More Negative Oxidation Potential than (+)-Catechin as an Electron-Transfer Antioxidant against a Peroxyl Radical
Nakanishi, I.; Ohkubo, K.; Miyazaki, K.; Hakamata, W.; Urano, S.; Ozawa, T.; Okuda, H.; Fukuzumi, S.; Ikota, N.; Fukuhara, K.
Chem. Res. Toxicol. 2004, 17, 26-31. - Production of Ultra-Long Lived Charge-Separated State in Zinc Chlorin-C60 Dyad Produced by One-Step Photoinduced Electron Transfer
Ohkubo, K.; Shao, J.; Ou, Z.; Kadish, K. M.; Li, G.; Pandey, R. K.; Fujitsuka, M.; Ito, O.; Imahori, H.; Fukuzumi, S.
Angew. Chem., Int. Ed. 2004, 43, 853-856.
(Selected as a VIP paper) - Quantitative Evaluation of d-p Interaction in Copper(I) Complexes and Control of Copper(I)-Dioxygen Reactivity
Osako, T.; Tachi, M.; Doe, M.; Shiro, M.; Ohkubo, K.; Fukuzumi, S.; Itoh, S.
Chem. Eur. J. 2004, 10, 237-246.
2003
- Metal-Centered Photoinduced Electron Transfer Reduction of a Gold(III) Porphyrin Cation Linked with a Zinc Porphyrin to Produce a Long-Lived Charge-Separated State in Non-Polar Solvents
Fukuzumi, S.; Ohkubo, K.; E, W.; Ou, Z.; Shao, J.; Kadish, K. M.; Hutchison, J. A.; Ghiggino, K. P.; Sintic, P. J.; Crossley, M. J.
J. Am. Chem. Soc. 2003, 125, 14984-14985. - Proton-Coupled Electron Transfer in a Ru(II)-Pterin Complex
Kojima, T.; Sakamoto, T.; Matsuda, Y.; Ohkubo, K.; Fukuzumi, S.
J. Inorg. Biochem. 2003, 96, 170. - Oxidation Mechanism of Phenols by Dicopper-Dioxygen (Cu/O2) Complexes
Osako, T.; Ohkubo, K.; Taki, M.; Tachi, Y.; Fukuzumi, S.; Itoh, S.
J. Inorg. Biochem. 2003, 96, 207. - Effects of Intramolecular Hydrogen Bonding on Electron Transfer Properties of Bisphenol Derivatives in Relation to Their Developing Properties in Silver Salt Photothermographic Systems
Akahori, H.; Morita, K.; Nishijima, A.; Mitsuhashi, T.; Ohkubo, K.; Fukuzumi, S.
J. Soc. Photogr. Sci. Technol. Jpn. 20033, 66, 491-496. - Driving Force Dependence of Photoinduced Electron Transfer Dynamics of Intercalated Molecules in DNA
Fukuzumi, S.; Nishimine, M.; Ohkubo, K.; Tkachenko, N. V.; Lemmetyinen, H.
J. Phys. Chem. B 2003, 107, 12511-12518. - Selective Oxygenation of Ring-Substituted Toluenes with Electron Donating and Withdrawing Substituents by Molecular Oxygen via Photoinduced Electron Transfer
Ohkubo, K.; Suga, K.; Morikawa, K.; Fukuzumi, S.
J. Am. Chem. Soc. 2003, 125, 12850-12859. - Ultrafast Photodynamics of Exciplex Formation and Photoinduced Electron Transfer in Porphyrin-Fullerene Dyads Linked at Close Proximity
Tkachenko, N. V.; Lemmetyinen, H.; Sonoda, J.; Ohkubo, K.; Sato, T.; Imahori, H.; Fukuzumi, S.
J. Phys. Chem. A 2003, 107, 8834-8844. - Fluorinated Photosensitizers: Synthesis, Photophysical, Electrochemical, Intracellular Localization and In-Vitro Photosensitizing Efficacy and Determination of Tumor-Uptake by 19F In-Vivo NMR Spectroscopy
Pandey, S. K.; Gryshuk, A. L.; Graham, A.; Ohkubo, K.; Fukuzumi, S.; Dobhal, M.; Zheng, G.; Ou, Z.; Zhan, R.; Kadish, K. M.; Oseroff, A.; Ramaprasad, S.; Pandey, R. K.
Tetrahedron 2003, 59, 10059-10073. - Oxidation Mechanism of Phenols by Dicopper-Dioxygen (Cu2/O2) Complexes
Osako, T.; Ohkubo, K.; Taki, M.; Tachi, Y.; Fukuzumi, S.; Itoh, S.
J. Am. Chem. Soc. 2003, 125, 11027-11033. - Synthesis and Characterization of a Novel Ruthenium-Pterin Complex Showing Proton-coupled Electron Transfer
Kojima, T.; Sakamoto, T.; Matsuda, Y.; Ohkubo, K.; Fukuzumi, S.
Angew. Chem., Int. Ed. 2003, 42, 4951-4954. - The Role of Electron Transfer Processes in Reactions of Diarylcarbenium Ions and Related Quinone Methides with Nucleophiles
Ofial, A. R.; Ohkubo, K.; Fukuzumi, S.; Lucius, R.; Mayr, H.
J. Am. Chem. Soc. 2003, 125, 10906-10912. - Long-Lived Charge-Separated State Produced by Photoinduced Electron Transfer in a Zinc Imidazoporphyrin-C60 Dyad
Kashiwagi, Y.; Ohkubo, K.; McDonald, J. A.; Blake, I. M.; Crossley, M. J.; Araki, Y.; Ito, O.; Imahori, H.; Fukuzumi, S.
Org. Lett. 2003, 5, 2719-2721. - Fast Self-Exchange Electron Transfer and Delocalization of Unpaired Electron between Zinc Porphyrin Radical Cations and Zinc Porphyrins
Fukuzumi, S.; Hasobe, T.; Endo, Y.; Ohkubo, K.; Imahori, H.
J. Porphyrins Phthalocyanines 2003, 7, 328-336. - Structure and Photoelectrochemical Properties of ITO Electrodes Modified with Self-Assembled Monolayers of meso,meso-Linked Porphyrin Oligomers
Hasobe, T.; Imahori, H.; Ohkubo, K.; Yamada, H.; Sato, T.; Nishimura, Y.; Yamazaki, I.; Fukuzumi, S.
J. Porphyrins Phthalocyanines 2003, 7, 296-312. - Reversed Effects of DNA on Hydride Transfer and Electron Transfer Reactions of Acridinium and Quinolinium Ions
Nishimine, M.; Ohkubo, K.; Komori, T.; Fukuzumi, S.
Chem. Commun. 2003, 1886-1887. - Rational Design Principle for Modulating Fluorescence Properties of Fluorescein-based Probes by Photoinduced Electron Transfer
Miura, T.; Urano, Y.; Tanaka, K.; Nagano, T.; Ohkubo, K.; Fukuzumi, S.
J. Am. Chem. Soc. 2003, 125, 8666-8671. - Diels-Alder Reactions of Anthracenes with Dienophiles via Photoinduced Electron Transfer
Fukuzumi, S.; Okamoto, T.; Ohkubo, K.
J. Phys. Chem. A 2003, 107, 5412-5418. - a-Methylstyrene with Molecular Oxygen, Catalyzed by 10-Methylacridinium Ion via Photoinduced Electron Transfer
Suga, K.; Ohkubo, K.; Fukuzumi, S.
J. Phys. Chem. A 2003, 107, 4339-4346. - Efficient cumylperoxyl radical-scavenging ability of artepillin C via direct one-step hydrogen-atom transfer
Nakanishi, I.; Uto, Y.; Ohkubo, K.; Ozawa, T.; Fukuhara, K.; Fukuzumi, S.; Nagasawa, H.; Hori, H.; Ikota, N.
Org. Biomol. Chem. 2003, 1, 1452-1453. - Quantitative Evaluation of Lewis Acidity of Metal Ions with Different Ligands and Counterions in Relation to the Promoting Effects of Lewis Acids on Electron Transfer Reduction of Oxygen
Ohkubo, K.; Menon, S. C.; Orita, A.; Otera, J.; Fukuzumi, S.
J. Org. Chem. 2003, 68, 4720-4726. - Remarkable Effects of Counter Ions on Scandium Ion-Promoted Electron Transfer Reactions
Yuasa, J.; Suenobu, T.; Ohkubo, K.; Fukuzumi, S.
Chem. Commun. 2003, 1070 -1071. - Electrodes Modified with meso,meso-Linked Porphyrin Oligomers
Hasobe, T.; Imahori, H.; Yamada, H.; Sato, T.; Ohkubo, K.; Fukuzumi, S.
Nano Lett. 2003, 3, 409-412. - Electron Transfer Properties of Bisphenol Derivatives in Relation with the Developing Properties in Silver Salt Photothermographic Systems
Akahori, H.; Morita, K.; Nishijima, A.; Mitsuhashi, T.; Ohkubo, K.; Fukuzumi, S.
J. Imag. Sci. Tech. 2003, 47, 124-132. - Driving Force Dependence of Intermolecular Electron Transfer Reactions of Fullerenes
Fukuzumi, S.; Ohkubo, K.; Imahori, H.; Guldi, D. M.
Chem. Eur. J. 2003, 9, 1585-1593. - A Planar Catechin Analogue as a Promising Antioxidant with Reduced Prooxidant Activity
Fukuhara, K.; Nakanishi, I.; Shimada, T.; Ohkubo, K.; Miyazaki, K.; Hakamata, W.; Urano, S.; Ikota, N.; Ozawa, T.; Okuda, H.; Miyata, N.; Fukuzumi, S.
Chem. Res. Toxicol. 2003, 16,81-86.
2002
- Metal Ion-Catalyzed Diels-Alder and Hydride Transfer Reactions. Catalysis of Metal Ions in the Electron Transfer Step
Fukuzumi, S.; Ohkubo, K.; Okamoto, T.
J. Am. Chem. Soc. 2002, 124, 14147-14155. - A Key Role for Old Yellow Enzyme in the Metabolism of Drugs by Trypanosoma Cruzi
Kubata, B. K.; Kabututu, Z.; Nozaki, T.; Munday, C. J.; Fukuzumi, S.; Ohkubo, K.; Lazarus, M.; Maruyama, T.; Martin, S. K.; Duszenko, M.; Urade, Y.
J. Exp. Med. 2002, 196,1241-1251. - Effects of Metal Ions Distinguishing Between One-Step Hydrogen- and Electron-Transfer Mechanisms for the Radical-Scavenging Reaction of (+)-Catechin
Nakanishi, I.; Miyazaki, K.; Shimada, T.; Ohkubo, K.; Urano, S.; Ikota, N.; Ozawa, T.; Fukuzumi, S.; Fukuhara, K.
J. Phys. Chem. A 2002, 106,11123-11126. - Small Reorganization Energy of Intramolecular Electron Transfer in Fullerene-Based Dyads with Short Linkage
Ohkubo, K.; Imahori, H.; Shao, J.; Ou, Z.; Kadish, K. M.; Chen, Y.; Pandey, R. K.; Fujitsuka, M.; Ito, O.; Fukuzumi, S.
J. Phys. Chem. A 2002, 106, 10991-10998. - Direct Detection of Superoxide Anion Generated in C60-Photosensitized Oxidation of NADH and an Analogue by Molecular Oxygen
Nakanishi, I.; Ohkubo, K.; Fujita, S.; Fukuzumi, S.; Konishi, T.; Fujitsuka, M.; Ito, O.; Miyata, N.
J. Chem. Soc. Perkin Trans. 2 2002, 1829-1833. - Fluorescence Maxima of 10-Methylacridone-Metal Ion Salt Complexes: A Convenient and Quantitative Measure of Lewis Acidity of Metal Ion Salts
Fukuzumi, S.; Ohkubo, K.
J. Am. Chem. Soc. 2002, 124,10270-10271. - Electron Transfer Reduction of a Highly Electron-Deficient Fullerene, C60F18 Ohkubo, K.; Taylor, R.; Boltalina, O. V.; Ogo, S.; Fukuzumi, S.
Chem. Commun. 2002, 1952-1953. - Effects of magnesium ion on kinetic stability and spin distribution of phenoxyl radical derived from a vitamin E analogue: mechanistic insight into antioxidative hydrogen-transfer reaction of vitamin E
Nakanishi, I.; Fukuhara, K.; Shimada, T.; Ohkubo, K.; Iizuka, Y.; Inami, K.; Mochizuki, M.; Urano, S.; Itoh, S.; Miyata, N.; Fukuzumi, S.
J. Chem. Soc. Perkin Trans. 2 2002, 1520-1524. - Photophysical and Electrochemical Properties of New Bacteriochlorins and Characterization of Radical Cation and Radical Anion Species
Fukuzumi, S.; Ohkubo, K.; Chen, Y.; Pandey, R. K.; Zhan, R.; Shao, J.; Kadish, K. M.
J. Phys. Chem. A 2002, 106,5105-5113. - DNA Cleavage via Superoxide Anion Formed in Photoinduced Electron Transfer from NADH to g-Cyclodextrin-Bicapped C60 in an Oxygen-Saturated Aqueous Solution
Nakanishi, I.; Fukuzumi, S.; Konishi, T.; Ohkubo, K.; Fujitsuka, M.; Ito, O.; Miyata, N.
J. Phys. Chem. B 2002, 106, 2372-2380. - Evidence that Gold(III) Porphyrins Are NOT Electrochemically Inert: Facile Generation of Gold(II) 5,10,15,20-Tetrakis(3,5-di-tert-butylphenyl)porphyrin
Kadish, K. M.; Wenbo, E.; Ou, Z.; Shao, J.; Sintic, P. J.; Ohkubo, K.; Fukuzumi, S.; Crossley, M. J.
Chem. Commun. 2002, 356-357.
2001
- Superoxide Anion Generation via Electron-Transfer Oxidation of Catechin Dianion by Molecular Oxygen in an Aprotic Medium
Nakanishi, I.; Fukuhara, K.; Ohkubo, K.; Shimada, T.; Kansui, H.; Kurihara, M.; Urano, S.; Fukuzumi, S.; Miyata, N.
Chem. Lett. 2001, 1152-1153. - Efficient Catalysis of Rare-Earth Metal Ions in Photoinduced Electron-Transfer Oxidation of Benzyl Alcohols by a Flavin Analogue
Fukuzumi, S.; Yasui, K.; Suenobu, T.; Ohkubo, K.
J. Phys. Chem. A 2001, 105, 10501-10510. - Photochemical and Electrochemical Properties of Zinc Chlorin-C60 Dyad as Compared to Corresponding Free-Base Chlorin-C60, Free-Base Porphyrin-C60 and Zinc Porphyrin-C60 Dyads
Fukuzumi, S.; Ohkubo, K.; Imahori, H.; Shao, J.; Ou, Z.; Zheng, G.; Chen, Y.; Pandey, R. K.; Fujitsuka, M.; Ito, O.; Kadish, K. M.
J. Am. Chem. Soc. 2001, 123, 10676-10683. - Quantitative Evaluation of Lewis Acidity of Organotin Compounds and the Catalytic Reactivity in Electron Transfer
Ohkubo, K. Suenobu, T.; Imahori, T.; Orita, A.; Otera, J.; Fukuzumi, S.
Chem. Lett. 2001, 978–979. - Photoalkylation of 10-Alkylacridinium Ion via Charge-Shioft Type of Photoinduced Electron Transfer Controlled by Solvent Polarity
Fukuzumi, S.; Ohkubo, K.; Suenobu, T.; Kato, K.; Fujitsuka, M.; Ito, O.
J. Am. Chem. Soc. 2001, 123, 8459-8467. - Comparison between Electron Transfer and Nucleophilic Reactivities of Ketene Silyl Acetals with Cationic Electrophiles.
Fukuzumi, S.; Ohkubo, K.; Otera, J.
J. Org. Chem. 2001, 66, 1450-1454. - Photochemical Generation of Cyclopentadienyliron Dicarbonyl Anion by an NAD Dimer Analogue.
Fukuzumi, S.; Ohkubo, K.; Fujitsuka, M.; Ito, O.; Teichmann, M. C.; Maisonhaute, E.; Amatore, C.
Inorg. Chem. 2001, 40, 1213-1219. - Regioreversed Thermal and Photochemical Reduction of 10-Methylacridinium and 1-Methylquinolinium Ions by Organosilanes and Oraganostannanes.
Fukuzumi, S.; Fujita, M.; Noura, S.; Ohkubo, K.; Suenobu, T.; Araki, Y.; Ito, O.
J. Phys. Chem. A 2001, 105, 1857-1868.
2000
- CO Sensing and Regulation of Gene Expression by the Transcriptional Activator CooA.
Aono, S.; Honma, Y.; Ohkubo, K.; Tawara, T.; Kamiya, T.; Nakajima, H.
J. Inorg. Biochem. 2000, 82, 51-56. - 100% Selective Oxygenation of p-Xylene to p-Tolualdehyde via Photoinduced Electron Transfer
Ohkubo, K. Fukuzumi, S.
Org. Lett. 2000, 2, 3647-3650. - Quantitative Evaluation of Lewis Acidity of Metal Ions Derived from the g-Values of ESR Spectra of Superoxide-Metal Ion Complexes in Relation with the Promoting Effects in Electron Transfer Reactions.
Fukuzumi, S.; Ohkubo, K.
Chem.-Eur. J. 2000, 6, 4532-4535. - Hydride Transfer from 9-Substituted 10-Methyl-9,10-dihydroacridines to Hydride Acceptors via Charge-Transfer Complexes and Sequential Electron-Proton-Electron Transfer. A Negative Temperature Dependence of the Rates
Fukuzumi, S.; Ohkubo, K.; Tokuda, Y.; Suenobu, T.
J. Am. Chem. Soc. 2000, 122, 4286-4294. - Photoalkylation of C60 by Alkylcobalt(III) Complexes.
Ohkubo, K.; Fukuzumi, S.
Inorg. React. Mech. 2000, 2, 147-153.
1998
- Redox-Controlled Ligand Exchange of the Heme in the CO-sensing Transcriptional Activator CooA.
Aono, S.; Ohkubo, K.; Nakajima, H.
J. Biol. Chem. 1998, 273, 25757-25764. - Heme Environmental Structure of CooA Is Modulated by the Target DNA Binding. Evidence from Resonance Raman Spectroscopy and CO Rebinding Kinetics.
Uchida, T.; Takahashi, S.; Ishimori, K, Morishima, I.; Ohkubo, K.; Nakajima, H.; Aono, S.
J. Biol. Chem. 1998, 273, 19988-19992.
1997
- A Carbon Monoxide Dependent Transcriptional Regulator Which Contains b-type Heme as a Carbon Monoxide Sensor.
Aono, S.; Ohkubo, K.; Matsuo, T.; Okada, M.; Nakajima, H.
J. Inorg. Biochem. 1997, 67, 362. - Signal Transduction in the Transcriptional Activator CooA Containing a Heme-Based CO Sensor: Isolation of a Dominant Positive Mutant which is Active as the Transcriptional Activator Even in the Absence of CO.
Aono, S.; Matsuo, T. Shimono, T.; Ohkubo, K.; Takasaki, H.; Nakajima, H.
Biochem. Biophys. Res. Commun. 1997, 240, 783-786.
和文原著論文
- Selective Oxygenation by Electron Transfer
Ohkubo, K.; Fukuzumi, S.
J. Synth. Org. Chem. Jpn. (有機合成化学協会誌)2012, 70, 343-353. - Highly Selective Photocatalytic Oxygenation with Molecular Oxygen as an Oxidant
Ohkubo, K.; Fukuzumi, S.
光化学協会誌 2010, 41, 73-76. - 水溶液中の核酸塩基およびDNAの電子移動酸化特性とDNA損傷機構
大久保 敬・福住俊一
アクア 2006, 32-33.
総説
- Chlorine-radical-mediated C–H Oxygenation Reaction Under Light Irradiation
Itabashi, Y.; Asahara, H.; Ohkubo, K.
Chem. Commun. 2023, 59, 7506–7517. - Lewis Acid-Coupled Electron Transfer of Metal-Oxygen Intermediates
Fukuzumi, S.; Ohkubo, K.; Lee, Y.-M.; Nam, W.
Chem. Eur. J. 2015, 21, 17548-17559. - One-Step Selective Hydroxylation of Benzene to Phenol
Fukuzumi, S.; Ohkubo, K.
Asian J. Org. Chem. 2015, 4, 836-845 (Focus Review).
Selected as a VIP paper - Efficient Charge Separation in Li+@C60 Supramolecular Complexes with Electron Donors
Kawashima, Y.; Ohkubo, K.; Fukuzumi, S.
Chem. Asian J. 2015, 10, 44-54.
Selected as an Feature Article - Organic Synthetic Transformations using Organic Dyes as Photoredox Catalysts
Fukuzumi, S.; Ohkubo, K.
Org. Biomol. Chem. 2014, 12, 6059-6071. - Long-Lived Charge Separation and Applications in Artificial Photosynthesis
Fukuzumi, S.; Ohkubo, K.; Suenobu, T.
Acc. Chem. Res. 2014, 47, 1455-1464. - Long-lived Photoinduced Charge Separation for Solar Cell Applications in Supramolecular Complexes of Multi-metalloporphyrins and Fullerenes
Fukuzumi, S.; Ohkubo, K.
Dalton Trans. 2013, 42, 15846-15858. - Selective Photocatalytic Reactions with Organic Photocatalysts
Fukuzumi, S.; Ohkubo, K.
Chem. Sci. 2013, 4, 561-574. - Mechanisms of Metal Ion-coupled Electron Transfer
Fukuzumi, S.; Ohkubo, K.; Morimoto, Y.
Phys. Chem. Chem. Phys. 2012, 14, 8472-8484. - Assemblies of Artificial Photosynthetic Reaction Centres
Fukuzumi, S.; Ohkubo, K.
J. Mater. Chem. 2012, 22, 4575-4587.
Selected as a Back Cover
Selected as a Hot Reviews - Catalytic Mechanisms of Hydrogen Evolution with Homogeneous and Heterogeneous Catalysts
Fukuzumi, S.; Yamada, Y.; Suenobu, T.; Ohkubo, K.; Kotani, H.
Energy Environ. Sci. 2011, 4, 2754-2766. - Metal Ion-Coupled and Decoupled Electron Transfer
Fukuzumi, S.; Ohkubo, K.
Coord. Chem. Rev. 2010, 254, 372-385. - Rational Design and Functions of Electron Donor-Acceptor Dyads with Much Longer Charge-Separated Lifetimes than Natural Photosynthetic Reaction Centers
Ohkubo, K.; Fukuzumi, S.
Bull. Chem. Soc. Jpn. 2009, 82, 303-315. - Long-Lived Charge-Separated States of Simple Electron Donor-Acceptor Dyads using Porphyrins and Phthalocyanines
Ohkubo, K.; Fukuzumi, S.
J. Porphyrins Phthalocyanines 2008, 12, 993-1004. - Formation of Superoxide-Metal Ion Complexes and the Electron Transfer Catalysis
Fukuzumi, S.; Ohtsu, H.; Ohkubo, K.; Itoh, S.; Imahori, H.
Coord. Chem. Rev. 2002, 226, 71-80.
著書・解説
- バイオガス中メタンからの常温常圧メタノール・ギ酸変換
大久保 敬
環境システム計測制御学会誌「EICA」, 2025, Vol. 29, in press - メタン光酸化によるカーボンニュートラル循環型酪農システム
大久保 敬
日本太陽エネルギー学会誌, 2024, Vol. 50, No.3, 55-61 - 二酸化塩素によるメタンの常温・常圧酸化
大久保 敬
日本エネルギー学会機関誌えねるみくす, 2024, Vol. 103, 657-663 - 光を用いた炭化水素のC-H酸素化反応
大久保 敬
THE CHEMICAL TIMES 関東化学(株), 2023, Vol. 4, pp. 7-13 - 光酸化によるプラスチック表面への極性官能基導入
大久保 敬
高分子材料の表面改質技術, シーエムシー出版, 第II編, 2023, 第5章, pp. 62-70 - 光化学反応による高分子材料の表面改質
大久保 敬
ぬれ性の制御と表面処理・改質技術, 技術情報協会,2023, 第3章, 第13節 - 亜塩素酸塩の活性化によるメタンからメタノール製造
大久保 敬
配管技術, 2022, 64, no. 10, 19-24. - バイオガスを液体燃料へ ~カーボンニュートラル循環型酪農~
大久保 敬
月刊バイオインダストリー, シーエムシー出版, 2022, vol. 39., no. 9. , 1-7. - メタン酸化によるメタノール・ギ酸合成〜カーボンニュートラル循環型酪農システムへの展開〜
大久保 敬
2050年カーボンニュートラルを目指す最新の触媒技術, CMCリサーチ, 2022, Chapter 4. - バイオガス中のメタンガスを常温・常圧光反応でメタノールとギ酸に変換する新技術
大久保 敬
化学装置, 日本工業出版株式会社, 2022, vol. 64, no. 8, 66-72 - 光でプラスチック表面を機能化する技術<驚異の酸化剤:二酸化塩素>
大久保 敬
月刊プラスチックス, 2022, no. 4 - 除菌消臭剤の有効成分である二酸化塩素を用いたプラスチック表面CH酸化反応
大久保 敬
接着の技術, 2021, vol. 40, no. 4. - 低コスト・高効率で家畜ふん尿からメタノール・ギ酸合成
大久保 敬
配管技術, 日本工業出版株式会社, 2020, 62, 15-19 - 酪農地帯が世界のエネルギー問題を解決する!?空気とメタンから低負荷で液体燃料を製造する夢の反応
大久保 敬
大阪大学News Letter, 2019, Autumn, 3-4. - 光でプラスチック表面を簡単に機能化〜二酸化塩素で表面を酸化する新技術〜
大久保 敬
プラスチックエージ, 2019, No. 9 - 炭化水素の酸素酸化を可能にするハイブリッド光触媒系の開発
大久保 敬
新学術領域「ハイブリッド触媒」ニュースレター, 2019, No. 4 - 有機フォトレドックス触媒を用いたメタルフリー有機合成反応
大久保 敬
光化学協会誌, 2019, No. 4 - 有機フォトレドックス触媒を用いた選択的酸化反応
大久保 敬
月刊「化学工業」2018, No.11, 化学工業社 - メタンからメタノール・ギ酸への選択的空気酸化〜除菌消臭剤に含まれていた成分が反応の鍵〜
大久保 敬
月刊クリーンエネルギー、2018, No.10, 日本工業出版 - メタンと空気からメタノール合成
大久保 敬
月刊ケミカルエンジニアリング, 化学工業社, 2018, Vol. 63, No. 6, pp. 6-10. - CO2を排出せずにメタンをメタノールへ変換−常温・常圧・酸素によるメタン酸化反応−
大久保 敬
月刊化学, 化学工業社, 2018, Vol. 73, No. 4, pp. 21-24. - 「新生物無機化学」伊東忍・林高史・青野重利 監修
第5章 電荷分離系
大久保 敬, 三共出版、2016 - p-Chloranil
Ohkubo, K.; Fukuzumi, S.
Encyclopedia of Reagents for Organic Synthesis: Fuchs, P. Ed., John Wiley & Sons, 2015. - リチウムイオン内包フラーレンの電子移動化学 (in Japanese)
Ohkubo, K.; Kawashima Y.; Fukuzumi, S.
有機化学情報誌「Organic Square」, 2014. - 「フラーレン誘導体・内包技術の最前線」Matsuo, Y. Ed. (in Japanese)
Chapter 3, 5.1「リチウムイオン内包フラーレンの光電子移動反応」
Ohkubo, K.; Kawashima Y.; Fukuzumi, S., CMC出版 , 2014, pp. 126-134. - 「人工光合成−システム構築に向けての最新技術動向と展望−」Fukuzumi, S. Ed. (in Japanese)
第3章「光捕集と光電荷分離」
Ohkubo, K.; Fukuzumi, S., CMC出版 , 2013 - 9-Mesityl-10-methylacridinium Perchlorate
Ohkubo, K.; Fukuzumi, S.
Encyclopedia of Reagents for Organic Synthesis: Fuchs, P. Ed., John Wiley & Sons, 2012. - Photoinduced Reactions of Radical Ions via Charge Separation
Fukuzumi, S.; Ohkubo, K.
Encyclopedia of Radical in Chemistry. Biology and Materials: Chatgilialoglu, C.; Studer, A. Eds., John Wiley & Sons Ltd, Chichester, UK, pp. 365-394, 2012.
特許
- 炭化水素またはその誘導体の酸化反応生成物の製造方法(特願2020-525753, 2019/6/18出願;特許第7178119号 2022/11/16登録)大久保敬
- ポリマー成形体への目的分子の選択的な結合方法、およびそれを用いた目的分子結合型ポリマーの製造方法(特願2019-569644, 2019.02.05出願、PCT/JP2019/004063, 11326035(US)(2022/5/10登録))大久保敬、淺原時泰、井上豪、高森清人
- 炭素同素体表面が改質された物質の製造方法、炭素同素体表面に官能基が導入された物質の製造方法、クライオ電子顕微鏡用グリッドの製造方法、有機物質、クライオ電子顕微鏡用グリッド(特願2019-061938, 2019.03.27出願)(PCT/JP2020/014148, 2020.03.27出願)井上 豪、淺原時泰、大久保 敬、岩崎憲治、宮崎直幸、廣瀬未果、中川敦史、髙木淳一、土井健史、安達宏昭、難波啓一、加藤貴之、牧野文信、藤田純三、熊野翔太
- ポリマー体、およびその製造方法(特願2018-117224, 2018.06.20出願) 大久保 敬、淺原時泰、井上豪、原田 信幸、中村 潤一、川瀬 建夫
- 変性膜の製造方法(特願2018-117355 2018.06.20出願 特許第07212878号 2023年1月18日) 大久保 敬、淺原時泰、中谷賢太、伊東祐一、水田康司、丸子 展弘、田原 修二
- 成形用型の製造方法(特願2018-117360 2018.06.20出願) 大久保 敬、淺原時泰、中谷賢太、伊東祐一、水田康司、中島 真実
- 変性製布の製造方法(特願2018-117359 2018.06.20出願) 大久保 敬、淺原時泰、中谷賢太、伊東祐一、水田康司
- 変性フィルムの製造方法(特願2018-117358 2018.06.20出願 特許第07212877号 2023.1.18) 大久保 敬、淺原時泰、中谷賢太、伊東祐一、水田康司
- 光学材料の製造方法(特願2018-117357 2018.06.20出願) 大久保 敬、淺原時泰、中谷賢太、伊東祐一、水田康司、山田孝裕
- 材料改質用変性粒子の製造方法(特願2018-117356 2018.06.20出願) 大久保 敬、淺原時泰、中谷賢太、伊東祐一、水田康司、木津 巧一
- 炭化水素またはその誘導体の酸化反応生成物の製造方法(特願2018-117453 2018.06.20出願、特許第7210007号, 2023.1.13登録) 大久保 敬、高森 清人
- ポリマーと被接着物との接着積層体の製造方法(特願2018-117172 2018.06.20出願、国際出願PCT/JP2019/024504、特許第7333080号, 2023.8.16登録)大久保敬、淺原時泰、井上豪
- 眼装着用レンズの製造方法および眼装着用レンズ(特願2018-117454 2018.06.20出願)西田 幸二、馬場 耕一、高 静花、大久保 敬、淺原時泰、井上 豪、宇山 浩、麻生隆彬
- 表面処理ポリマーの製造方法、ポリマー、金属メッキ用ポリマー、金属メッキポリマーおよび接着積層体並びにそれらの製造方法(特願2018-096676 2018.05.18出願、特許第7336141号 2023.8.16登録、国際出願PCT/JP2019/019814, ZL201980033083.5(中国) 2023.1.17登録)麻生隆彬、淺原時泰、大久保 敬、井上 豪、宇山 浩
- ポリマーと被接着物との接着積層体の製造方法、ポリマーと被接着物との接着積層体製造用ポリマー、ポリマーと被接着物との接着積層体(特願2018-096677 2018.05.18出願 国際出願PCT/JP2019/019815)淺原時泰、麻生隆彬、大久保 敬、井上 豪、宇山 浩
- 高分子表面への機能性分子修飾技術(特願2018-018598、2018.2.5出願)大久保敬、淺原時泰、井上豪、高森清人
- ポリマー成形体の表面改質方法およびそれを用いた表面改質ポリマー成形体の製造方法 (特願2016-244690) 大久保 敬、井上 豪、水田 康司、伊東 祐一、高森清人
- プロピレングリコールの製造方法 (特願 2016-219094) 大久保 敬、高森清人
- エチレングリコールの製造方法 (特願 2016-219093) 大久保 敬、高森清人
- ジオールの製造方法 (特願 2016-219092, 特許第686068号) 大久保 敬、高森清人
- シクロヘキサンの酸化反応生成物の製造方法 (特願2016−042140, 特開2017-155020) 大久保 敬、柴田剛克、高森清人
- エタンの酸化反応生成物の製造方法 (特願2016−042139, 特開2017-1550219) 大久保 敬、柴田剛克、高森清人
- メタンの酸化反応生成物の製造方法 (特願2016−042138, 特開2017-155018) 大久保 敬、柴田剛克、高森清人
- 炭化水素またはその誘導体の酸化反応生成物の製造方法(特願2016−042137, 特開2017-155017, 特許第6080281号,US16/063103, EP16875772.2, CN201680074063.9, SA518391862, AEP6000799/2018) 大久保 敬、柴田剛克、高森清人
- オレフィンの酸化 (特願2015−248070, 特開2017-109979, 特許第6745452号, US10,947,190 B2(米国)) 大久保 敬、柴田剛克、高森清人
- 内包フラーレンを用いた光電変換装置
特許公開2015-069731
大久保 敬、福住俊一、川島雄樹、羽曾部 卓、酒井隼人 - 酸化触媒、フェノール類の製造方法、および過酸化水素の製造方法(特許第5470623号,特許公開2011-189224)
大久保 敬、福住俊一、小林崇希 - 光照射によって誘電率が変化する膜およびそれを用いた電子デバイス(出願番号:特願2009−205923)出願日:平成21年9月7日, 福住俊一、大久保敬、村上元信、村田英幸、酒井平祐
- 芳香族化合物の酸化反応生成物の製造方法(特許第5213142号, 出願番号:特願2009−213811)出願日:平成21年9月15日, 大久保 敬、福住俊一、水島健太郎
- 新規9-置換アクリジニウム誘導体、および9-置換アクリジニウム誘導体を用いた芳香族アルデヒドと過酸化水素の同時製造方法(特許公開2010-59141)
大久保 敬、福住俊一、岩田亮介、水島 健太郎、鈴木信夫、相馬和憲 - 水素発生触媒(出願番号:特願2007−247656)出願日:平成19年9月25日, 福住俊一、小谷弘明、大久保敬、花崎亮
- 新規クマリン誘導体(特許公開2008-214328)
大久保 敬、福住俊一、村上元信、鈴木信夫、相馬和憲 - キノリニウムイオン誘導体、キノリニウムイオン誘導体の製造方法、キノリニウムイオン誘導体を用いた製品、キノリニウムイオン誘導体を用いた還元方法および酸化方法(出願番号:PCT/JP2007/054152)出願日:平成18年9月8日, 福住俊一、小谷弘明、大久保敬
- フラビンおよびそれを用いた製品(出願番号:特願 2006−233186)出願日:平成18年8月30日, 福住俊一、大久保敬、村上元信
- 過酸化水素の製造方法(出願番号:特願2006−136990)出願日:平成18年5月16日,福住俊一、小谷弘明、大久保 敬
- 光触媒
特許公開2005-145853
福住俊一、大久保 敬 - 金属クロリン・フラーレン連結分子(特許第4417032号、出願番号:特願2003-156014)出願日:平成15年5月30日, 特許取得日:平成21年12月4日, 福住俊一,大久保 敬, Ravindra K. Pandey, Karl M. Kadish, Jianguo Shao, Guolin Li
受賞
- 2024年 令和6年度 科学技術分野の文部科学大臣表彰 科学技術賞
- 2019年 IAAM Award Lecture (International Association of Advanced Materials)
- 2018年 光化学協会賞(光化学協会)
- 2013年 大澤賞(フラーレン・ナノチューブ・グラフェン学会)
- 2013年 野副記念奨励賞(基礎有機化学会)
- 2013年 有機電子移動化学奨励賞(有機電子移動化学研究会)
- 2008年 APA Prize for Young Scientist(The Asian and Oceanian Photochemistry Association)
- 2008年 SPP-JPP Young Investigator Award in Porphyrin Chemistry (Society of Porphyrins and Phthalocyanines)
- 2007年 日本化学会進歩賞(日本化学会)
- 2007年 BCSJ Award Article(日本化学会・日本化学会欧文誌編集委員会)
- 2005年 光化学協会奨励賞(光化学協会)